Copper porphyrin-catalyzed cross dehydrogenative coupling of alkanes with carboxylic acids: Esterification and decarboxylation dual pathway,Tetrahedron

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Copper porphyrin-catalyzed cross dehydrogenative coupling of alkanes with carboxylic acids: Esterification and decarboxylation dual pathway
Tetrahedron ( IF 2.1 ) Pub Date : 2021-08-05 , DOI: 10.1016/j.tet.2021.132377
Xiao-Yan Chen ₁ , Shuang Yang ₁ , Bao-Ping Ren ₁ , Lei Shi ₂ , Dong-Zi Lin ₃ , Hao Zhang ₁ , Hai-Yang Liu ₁

Affiliation

A dual-functional copper porphyrin-catalyzed cross dehydrogenative coupling (CDC) of carboxylic acids with alkanes was reported firstly. The reaction gives allylic esters or alkylalkenes depending on the carboxylic acid substrates. Copper porphyrin catalyzed CDC method has the superiority of short reaction time, good functional group tolerance, base and solvent free, producing target products in an atom-economic manner.

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