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Rational assembly of metal-oxo clusters into molecular materials via a “wheel mounting” mode
Inorganic Chemistry Frontiers ( IF 6.1 ) Pub Date : 2021-07-23 , DOI: 10.1039/d1qi00779c
Hao Fu 1, 2, 3, 4 , Xin Wu 1 , Wei-Hui Fang 1 , Lei Zhang 1 , Fei Wang 1 , Jian Zhang 1
Affiliation  

We devised a new self-assembly method towards the construction of molecular materials via a “wheel mounting” mode of [Ti3M] (M = Co or Zn) clusters. Assembly of these clusters was designable and customizable into desirable size, shape, and properties. An optical-driven molecular transition was realized with the stimulus–response of photochromism. This work not only provides an approach towards predictable and designable clusters, it also establishes a cluster-based structural model of molecular materials.

中文翻译:

通过“轮安装”模式将金属-氧簇合理组装成分子材料

我们设计了一种新的自组装方法,通过[Ti 3 M](M = Co 或 Zn)簇的“轮安装”模式构建分子材料。这些集群的组装是可设计的,可定制为所需的尺寸、形状和特性。通过光致变色的刺激响应实现了光驱动的分子跃迁。这项工作不仅提供了一种可预测和可设计的簇的方法,还建立了基于簇的分子材料结构模型。
更新日期:2021-08-04
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