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Manipulating Chemical Processes by Pseudosolid Spatial Limitation
JACS Au Pub Date : 2021-08-03 , DOI: 10.1021/jacsau.1c00202
Shin Yi, Jia-Syuan Chen, Chang-Ming Wang, Wei-Ssu Liao

It is always preferred to perform chemical processes in liquid or gas phases because of the merits of operation convenience, reaction efficiency, and component homogeneity. However, tremendous efforts have to be made to purify the final product and minimize procedure losses unless a well-defined chemical mechanism is found. Herein, an unconventional chemical functioning system accommodating molecule-in-pseudosolid manipulation is reported. It entails the properties of enhanced molecular effective collision and directional guidance for delicate chemical reaction spatial controls. This design achieves facilitated rates on multicomponent chemical reactions with pros of unique simultaneous final product separation through intrapseudosolid spatial limitation. Localized homogeneous component mixing, pronounced molecular collision, and pure product separation happening in this action surmount the obstacles of conventional chemical operation with a straightforward sketch. A path toward fine chemistry is therefore paved, where traditional thoughts on beneficial reaction environments may be reconsidered.

中文翻译:

通过伪固体空间限制操纵化学过程

由于操作方便、反应效率和组分均匀性等优点,总是优选在液相或气相中进行化学过程。然而,除非找到明确定义的化学机制,否则必须付出巨大努力来纯化最终产品并将过程损失降至最低。在此,报道了一种非常规化学功能系统,可适应假固体中的分子操作。它需要增强分子有效碰撞和定向引导的特性,以实现精细的化学反应空间控制。这种设计通过内部假固体空间限制实现了多组分化学反应的促进速率,具有独特的同时最终产物分离的优点。局部均匀组分混合,明显的分子碰撞,在这个动作中发生的纯产品分离以简单的草图克服了传统化学操作的障碍。因此,为精细化学铺平了道路,可以重新考虑有关有益反应环境的传统思想。
更新日期:2021-09-27
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