Nature Reviews Chemistry ( IF 38.1 ) Pub Date : 2021-08-04 , DOI: 10.1038/s41570-021-00304-2 Vincent Trudel 1 , Chieh-Hung Tien 1 , Alina Trofimova 1 , Andrei K Yudin 1
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Interrupted reactions reroute established processes to new and often unanticipated end points. Of particular interest are the cases in which a known reactive intermediate takes on a new reaction pathway, either because this pathway is lower in energy or because the conventional pathway is no longer available. Through analysis of documented cases, we aim to dissect the known interrupted reactions and trace their mechanistic origins. As new chemical processes are being discovered at a seemingly ever-increasing pace, it is likely that new interrupted reactions will continue to emerge. Our hope is that the cases considered in this Review will help identify new classes of these fascinating transformations.
中文翻译：
化学合成中的中断反应
中断的反应将已建立的过程重新路由到新的且通常未预料到的终点。特别感兴趣的是已知反应中间体采用新反应途径的情况，因为该途径能量较低或因为常规途径不再可用。通过对记录在案的案例进行分析，我们旨在剖析已知的中断反应并追溯其机械起源。随着新化学过程的发现速度似乎越来越快，新的中断反应很可能会继续出现。我们希望本综述中考虑的案例将有助于确定这些迷人转变的新类别。
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