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Iron oxide (Fe3O4)-laden titanium carbide (Ti3C2Tx) MXene stacks for the efficient sequestration of cationic dyes from aqueous solution
Chemosphere ( IF 8.1 ) Pub Date : 2021-08-03 , DOI: 10.1016/j.chemosphere.2021.131679
Muruganantham Rethinasabapathy 1 , Gokul Bhaskaran 1 , Bumjun Park 1 , Jin-Yong Shin 2 , Woo-Sik Kim 3 , Jungho Ryu 4 , Yun Suk Huh 1
Affiliation  

We prepared two-dimensional (2D) stack-structured magnetic iron oxide (Fe3O4) nanoparticle anchored titanium carbide (Ti3C2Tx) MXene material (Ti3C2Tx/Fe3O4). It was used as a potential adsorbent to remove carcinogenic cationic dyes, such as methylene blue (MB) and rhodamine B (Rh B), from aqueous solutions. Ti3C2Tx/Fe3O4 exhibited maximum adsorption capacities of 153 and 86 mg g−1 for MB and Rh B dyes, respectively. Batch adsorption experimental data fits the Langmuir model well, revealing monolayer adsorption of MB and Rh B onto the adsorption sites of Ti3C2Tx/Fe3O4. Additionally, Ti3C2Tx/Fe3O4 showed rapid MB/Rh B adsorption kinetics and attained equilibrium within 45 min. Moreover, Ti3C2Tx/Fe3O4 demonstrated recyclability over four cycles with high stability due to the presence of magnetic Fe3O4 nanoparticles. Furthermore, it exhibited remarkable selectivities of 91% and 88% in the presence of co-existing cationic and anionic dyes, respectively. Given the extraordinary adsorption capacities, Ti3C2Tx/Fe3O4 may be a promising material for the effective removal of cationic dyes from aqueous media.



中文翻译:

载有氧化铁 (Fe3O4) 的碳化钛 (Ti3C2Tx) MXene 堆栈,用于从水溶液中有效螯合阳离子染料

我们制备了二维 (2D) 堆叠结构磁性氧化铁 (Fe 3 O 4 ) 纳米粒子锚定碳化钛 (Ti 3 C 2 T x ) MXene 材料 (Ti 3 C 2 T x /Fe 3 O 4 )。它被用作一种潜在的吸附剂,可从水溶液中去除致癌阳离子染料,如亚甲蓝 (MB) 和罗丹明 B (Rh B)。Ti 3 C 2 T x /Fe 3 O 4 的最大吸附容量分别为 153 和 86 mg g -1分别用于 MB 和 Rh B 染料。批量吸附实验数据很好地符合朗缪尔模型,揭示了 MB 和 Rh B 在 Ti 3 C 2 T x /Fe 3 O 4的吸附位点上的单层吸附。此外,Ti 3 C 2 T x /Fe 3 O 4显示出快速的MB/Rh B 吸附动力学并在45 分钟内达到平衡。此外,由于磁性 Fe 3 O的存在,Ti 3 C 2 T x /Fe 3 O 4表现出在四个循环中具有高稳定性的可回收性4个纳米粒子。此外,它在共存的阳离子和阴离子染料的存在下分别表现出 91% 和 88% 的显着选择性。鉴于非凡的吸附能力,Ti 3 C 2 T x /Fe 3 O 4可能是一种很有前途的材料,可有效去除水性介质中的阳离子染料。

更新日期:2021-08-09
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