Diverse functionalization of aryl halides mediated by bis(phenylsulfonyl)methane,Tetrahedron

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Diverse functionalization of aryl halides mediated by bis(phenylsulfonyl)methane
Tetrahedron ( IF 2.1 ) Pub Date : 2021-08-03 , DOI: 10.1016/j.tet.2021.132371
Ping Pan ₁ , Lei Chen ₁ , Xue-jing Zhang ₁ , Ming Yan ₁

Affiliation

A palladium-catalyzed coupling reaction of bis(phenylsulfonyl)methane and aryl halides was developed. A variety of bis(phenylsulfonyl)methyl arenes were prepared in good yields. The transformations of bis(phenylsulfonyl)methyl to methyl, trideuteriomethyl, ethyl, carboxyl, and other functional groups were demonstrated. The results provided a new approach to diverse functionalization of aryl halides.

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