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Ni-Catalyzed Reductive Carbonylation of Alkyl Halides to Form Dialkyl Ketones Using Diphenyl Oxalate as CO Surrogate
Synlett ( IF 1.7 ) Pub Date : 2021-07-14 , DOI: 10.1055/a-1550-7935
Yuren Sun , Lei Su , Ken Yao , Hegui Gong , Weiqi Tong

In this work, we disclosed that diphenyl oxalate serves as a CO surrogate to enable a Ni-catalyzed carbonylation of alkyl bromides/tosylates to afford dialkyl ketones. The reaction shows broad substrate scope and good functional group tolerance.

中文翻译:

使用草酸二苯酯作为 CO 替代物,镍催化烷基卤化物还原羰基化形成二烷基酮

在这项工作中,我们公开了草酸二苯酯作为 CO 替代物,使 Ni 催化的烷基溴化物/甲苯磺酸盐羰基化得到二烷基酮。该反应显示出广泛的底物范围和良好的官能团耐受性。
更新日期:2021-08-02
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