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Visible-light-induced 3d transition metal-catalysis: A focus on C–H bond functionalization
Current Opinion in Green and Sustainable Chemistry ( IF 9.3 ) Pub Date : 2021-07-30 , DOI: 10.1016/j.cogsc.2021.100539
Olivier Baslé 1
Affiliation  

Transition metal catalysis under visible-light irradiation has attracted considerable interest in recent years. With the objective of breaking free from the use of noble metals, and as an alternative to traditional photoredox and dual catalysis, the implementation of this strategy with 3d transition metal complexes capable of both absorbing visible light and enabling catalysis has very recently led to the development of efficient photocatalytic systems for challenging organic synthesis, including C–H bond functionalization reactions.



中文翻译:

可见光诱导的 3d 过渡金属催化:关注 C-H 键功能化

近年来,可见光照射下的过渡金属催化引起了相当大的兴趣。为了摆脱贵金属的使用,并作为传统光氧化还原和双催化的替代方案,利用能够吸收可见光和催化的 3d 过渡金属配合物实施这一策略最近导致了发展用于挑战有机合成的高效光催化系统,包括 C-H 键功能化反应。

更新日期:2021-08-31
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