The effect of V₂O₅ addition on sealing properties of glasses with nominal composition (29-x)SiO₂–23SrO–32BaO–4Al₂O₃–10B₂O₃–2P₂O₅-xV₂O₅ (where x = 2; 4; 6 mol.%) is reported. The glass transition temperature (T_g) decreases, and flow temperature increases with an increase in V₂O₅ content. ²⁹Si and ³¹P MAS-NMR indicate that silicates are present mainly as Q² groups, while phosphates are present as Q⁰ groups. ²⁷Al MAS-NMR data shows that Al is 4-coordinated with oxygens, and¹¹B NMR spectra show the presence of both BO₃ and BO₄ units. Composite materials were prepared by mixing glasses and vanadium di-boride VB₂ (15 vol%). Sealing with Crofer-22 alloy was carried out with composite and revealed good bonding and tight interfaces.

V ₂ O ₅添加对标称成分为 (29-x)SiO ₂ –23SrO–32BaO–4Al ₂ O ₃ –10B ₂ O ₃ –2P ₂ O ₅ -xV ₂ O ₅ (其中 x = 2；4；6 mol.%)。随着V ₂ O ₅含量的增加，玻璃化转变温度(T _g )降低，流动温度升高。²⁹ Si 和³¹ P MAS-NMR 表明硅酸盐主要以 Q ²基团存在，而磷酸盐以 Q 存在⁰组。²⁷ Al MAS-NMR 数据显示Al 与氧4-配位，¹¹ B NMR 谱显示BO ₃和BO ₄单元的存在。通过混合玻璃和二硼化钒VB ₂ (15 vol%)制备复合材料。使用复合材料进行 Crofer-22 合金的密封，并显示出良好的粘合和紧密的界面。