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Toluene abatement on Ag-CeO2/SBA-15 catalysts: synergistic effect of silver and ceria
Materials Today Chemistry ( IF 6.7 ) Pub Date : 2021-07-29 , DOI: 10.1016/j.mtchem.2021.100530
N.N. Mikheeva 1 , V.I. Zaikovskii 2, 3 , Y.V. Larichev 2, 3 , G.V. Mamontov 1
Affiliation  

As a typical volatile organic compound, toluene is a hazardous material for human health and the environment, and currently, the development of catalysts for its oxidation into CO2 and water is crucial. The series of Ag-CeO2/SBA-15 catalysts is synthesized by wetness impregnation techniques and characterized by a number of physical-chemical methods (nitrogen [N2] physisorption, small angle X-ray scattering [SAXS], transmission electron microscopy [TEM], and temperature-programmed reduction [TPR]). The toluene sorption and catalytic properties in toluene oxidation are studied. Small silver [Ag] and cerium oxide [ceria, CeO2] particles with sizes below 3 nm are predominantly formed in the ordered structure of Santa Barbara Amorphous-15 [SBA-15]. The interactions between the Ag and CeO2 nanoparticles are established. Temperature-programmed desorption of toluene [TPD-C7H8] analysis shows that physical adsorption of toluene occurs on pristine SBA-15 material, while the introduction of either silver or ceria to SBA-15 leads to the appearance of additional strongly bound chemisorbed toluene on such sites. When both Ag and CeO2 are introduced, only chemisorbed toluene is formed over the Ag-CeO2/SBA-15 catalyst, and the highest catalytic activity in toluene oxidation is observed over this catalyst (T98% = 233 °C, 0.2% C6H5CH3) that is attributed to the synergistic effect of ceria [CeO2] and silver [Ag].



中文翻译:

Ag-CeO2/SBA-15 催化剂上的甲苯减排:银和二氧化铈的协同作用

作为一种典型的挥发性有机化合物,甲苯是一种对人类健康和环境有害的物质,目前,开发将其氧化成 CO 2和水的催化剂至关重要。该系列Ag-CeO 2 /SBA-15催化剂采用湿浸渍技术合成,并通过多种物理化学方法(氮[N 2 ]物理吸附、小角X射线散射[SAXS]、透射电子显微镜[ TEM] 和程序升温还原 [TPR])。研究了甲苯氧化中甲苯的吸附和催化性能。小银 [Ag] 和氧化铈 [ceria, CeO 2]尺寸低于 3 nm 的颗粒主要在 Santa Barbara Amorphous-15 [SBA-15] 的有序结构中形成。建立了Ag和CeO 2纳米颗粒之间的相互作用。甲苯的程序升温解吸 [TPD-C 7 H 8 ] 分析表明甲苯的物理吸附发生在原始 SBA-15 材料上,而将银或二氧化铈引入 SBA-15 导致出现额外的强结合化学吸附甲苯在这些位置。当同时引入Ag 和 CeO 2 时,仅在 Ag-CeO 2 /SBA-15 催化剂上形成化学吸附甲苯,并且在该催化剂上观察到最高的甲苯氧化催化活性(T 98% = 233 °C, 0.2% C 6 H 5 CH 3 ),这归因于氧化铈 [CeO 2]和银 [Ag]的协同作用。

更新日期:2021-07-30
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