MOM group is one of the most commonly used protecting groups for alcohols. This study describes novel direct functionalization of the MOM-protected benzylic alcohols. Preparation of allylic compounds from benzyl MOM ethers was successfully achieved by utilization of allyltrimethylsilane and AlCl₃. In addition, direct azidation of benzyl MOM ethers using TMSN₃ was successful carried out under AlCl₃-mediated reaction conditions. These results demonstrate that this novel synthetic procedure is a promising approach to direct functionalization of MOM-protected alcohols including allylation and azidation.

中文翻译：

---

使用氯化铝进行 MOM 保护的苯甲醇的简便直接偶联反应

MOM 基团是最常用的醇类保护基团之一。本研究描述了 MOM 保护的苯甲醇的新型直接功能化。利用烯丙基_三甲基硅烷和AlCl ₃成功地从苄基MOM醚制备烯丙基化合物。此外，在AlCl ₃介导的反应条件下，使用TMSN ₃成功地进行了苄基MOM 醚的直接叠氮化。这些结果表明，这种新的合成程序是一种有前途的方法，可以直接将 MOM 保护的醇官能化，包括烯丙基化和叠氮化。