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Exploring the studies of charge transportation of an aromatic acid based Co(II)-Metallogel scaffold fabricated Schottky device
Journal of Physics and Chemistry of Solids ( IF 4.3 ) Pub Date : 2021-07-30 , DOI: 10.1016/j.jpcs.2021.110300
Amiya Dey 1 , Sayantan Sil 2 , Santanu Majumdar 1 , Rajib Sahu 3 , Madhuri Ghosh 1 , Gerald Lepcha 1 , Partha Pratim Ray 4 , Biswajit Dey 1
Affiliation  

An efficient supramolecular metallogel of Cobalt(II) has been synthesized through the ultra-sonication technique. Cobalt(II)-salt (Cobalt acetate tetrahydrate), organic acid like terephthalic acid along with N,N-dimethyl formamide solvent are the key ingredients of the Co(II)-metallogel. The rheology-based experimental values of storage and loss modulus of the Co(II)-metallogel prove the mechanical efficiency of the metallogel-material. The chemical compositions are found through elemental investigations. The infrared spectral results help to realize the metallogel formation strategy. The electrical characteristics of the synthesized metallogel have been properly investigated. The semiconducting feature of the metallogel-material has been experimentally verified. The measured current-voltage characteristics of Cobalt(II)-metallogel (Co-TA) based thin film type metal-semiconductor (MS) junction-device shows a non-linear rectifying behaviour, representing a Schottky diode (SD) performance with promising electronic charge transport property.



中文翻译:

探索基于芳香酸的 Co(II)-Metallogel 支架制造的肖特基器件的电荷传输研究

通过超声技术合成了一种高效的钴 (II) 超分子金属凝胶。Co(II)-盐(四水合醋酸钴)、有机酸如对苯二甲酸以及 N,N-二甲基甲酰胺溶剂是 Co(II)-金属凝胶的关键成分。Co(II)-金属凝胶的储能模量和损耗模量的基于流变学的实验值证明了金属凝胶材料的机械效率。化学成分是通过元素调查发现的。红外光谱结果有助于实现金属凝胶形成策略。合成的金属凝胶的电特性已得到适当研究。金属凝胶材料的半导体特性已通过实验验证。

更新日期:2021-08-01
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