Palladium(II)-Catalyzed N-Carbonylative Cross-Coupling Reaction of Sulfoximines with Aryl, Heteroaryl, and Alkenyl Halides Using Tungsten Hexacarbonyl as Carbon Monoxide Source,Asian Journal of Organic Chemistry

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Palladium(II)-Catalyzed N-Carbonylative Cross-Coupling Reaction of Sulfoximines with Aryl, Heteroaryl, and Alkenyl Halides Using Tungsten Hexacarbonyl as Carbon Monoxide Source
Asian Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2021-07-29 , DOI: 10.1002/ajoc.202100388
Sang Hoon Han ₁ , Kyungsup Lee ₁ , Hee Chan Noh ₁ , Phil Ho Lee ₁

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Palladium(II)-catalyzed N-acylation was demonstrated through the reaction of N−H sulfoximines with a variety of aryl, heteroaryl, and aryl halides using W(CO)₆ as a source of carbon monoxide, affording N-acylated sulfoximines in good to excellent yields. Moreover, alkenyl bromides underwent palladium(II)-catalyzed N-acylation reactions with N−H sulfoximines, leading to the formation of N-cinnamoyl sulfoximines.

中文翻译：

使用六羰基钨作为一氧化碳源，钯 (II) 催化亚砜亚胺与芳基、杂芳基和烯基卤化物的 N-羰基化交叉偶联反应

通过 N-H 亚砜亚胺与各种芳基、杂芳基和芳基卤化物的反应，使用 W(CO) ₆作为一氧化碳来源，证明了钯 (II) 催化的N-酰化，从而提供了良好的N-酰化亚砜亚胺以优异的产量。此外，烯基溴化物与 N-H 亚砜亚胺发生钯 (II) 催化的N-酰化反应，形成N-肉桂酰基亚砜亚胺。

更新日期：2021-09-13

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