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Influence of the Structure of Hydrophobic Porous Silica Materials of SBA-15 Type and Polymethylsiloxane Derivatives on the Value of Water Intrusion Pressure
Theoretical and Experimental Chemistry ( IF 1 ) Pub Date : 2021-07-29 , DOI: 10.1007/s11237-021-09682-6
M. M. Kurmach 1 , O. V. Shvets 1 , Z. V. Chernenko 1 , P. S. Yaremov 1 , S. V. Kolotilov 1 , N. N. Tsyrin 2 , A. V. Eroshenko 2 , L. S. Davydovskyi 3 , S. P. Bisyk 3 , A. M. Zhuchenko 4 , G. M. Melnichenko 4
Affiliation  

A series of silica mesoporous molecular sieves SBA-15 with a 7.7 ± 0.8 nm pore diameter, the surface of which is hydrophobized with methylsilyl groups, and polymethylsiloxane derivatives with a 1.6 ± 0.8 nm pore diameter were obtained. These sieves are characterized by X-ray phase analysis, adsorption of nitrogen at 77 K and water at 293 K, as well as IR spectroscopy. It is established that there is a significant resistance to water intrusion (absorption) only in the case of substances characterized by the nitrogen adsorption potential value ∆μ0 ≤ 6.4 kJ/mol. The studied systems can be used as “molecular springs” in shock load damping devices due to their functional properties.



中文翻译:

SBA-15型疏水多孔二氧化硅材料的结构和聚甲基硅氧烷衍生物对水侵入压力值的影响

获得了一系列孔径为7.7±0.8 nm、表面经甲基硅烷基团疏水化处理的二氧化硅介孔分子筛SBA-15,以及孔径为1.6±0.8 nm的聚甲基硅氧烷衍生物。这些筛子的特征在于 X 射线相分析、77 K 下的氮和 293 K 下的水吸附,以及红外光谱。确定只有在以氮吸附电位值 ∆μ 0 ≤ 6.4 kJ/mol为特征的物质的情况下,才具有显着的抗水侵入(吸收)能力。由于其功能特性,所研究的系统可用作冲击负载阻尼装置中的“分子弹簧”。

更新日期:2021-07-29
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