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Combustion method combined with sonochemical step for synthesis of maghemite-supported catalysts for the hydrogenation of 2,4-dinitrotoluene
Catalysis Communications ( IF 3.4 ) Pub Date : 2021-07-29 , DOI: 10.1016/j.catcom.2021.106342
Viktória Hajdu 1 , Gábor Muránszky 1 , Masahiro Hashimoto 2 , Ferenc Kristály 3 , Milán Szőri 1 , Béla Fiser 1 , Zoltán Kónya 4 , Béla Viskolcz 1 , László Vanyorek 1
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Maghemite particles were synthesized by using a combined combustion method and sonochemical step. Maghemite was used as carrier to prepare supported Pt and Pd catalysts after deposition via a sonochemical step. The catalysts were immediately ready to be used (metals were catalytically active) for the 2,4-dinitrotoluene hydrogenation to produce 2,4-toluenediamine. The most active catalysts were the Pd/maghemite and bimetallic Pd-Pt/maghemite. The catalysts were easily separable after reaction due to their magnetic properties.



中文翻译:

燃烧法结合声化学步骤合成磁赤铁矿负载的2,4-二硝基甲苯加氢催化剂

磁赤铁矿颗粒是通过使用组合燃烧法和声化学步骤合成的。在通过声化学步骤沉积后,磁赤铁矿被用作载体以制备负载的 Pt 和 Pd 催化剂。该催化剂可立即用于 2,4-二硝基甲苯加氢以生产 2,4-甲苯二胺(金属具有催化活性)。最活跃的催化剂是 Pd/磁赤铁矿和双金属 Pd-Pt/磁赤铁矿。由于其磁性,催化剂在反应后很容易分离。

更新日期:2021-08-03
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