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Atomic Layer Deposition Plasma-Based Undoped-HfO2 Ferroelectric FETs for Non-Volatile Memory
IEEE Electron Device Letters ( IF 4.9 ) Pub Date : 2021-06-28 , DOI: 10.1109/led.2021.3092787
Jun-Dao Luo , Yu-Ying Lai , Kuo-Yu Hsiang , Chia-Feng Wu , Hao-Tung Chung , Wei-Shuo Li , Chun-Yu Liao , Pin-Guang Chen , Kuan-Neng Chen , Min-Hung Lee , Huang-Chung Cheng

A plasma-based undoped-HfO 2 FeFET (ferroelectric FET) with non-volatile memory characteristics is demonstrated. Modifying the O 2 plasma period in plasma-enhanced atomic layer deposition (PE-ALD) is an effective approach to enhance the remnant polarization ( $\text{P}_{\text {r}}$ ) up to 2P $_{\text {r}} = 25\,\,\mu \text{C}$ /cm 2 for the MFM (metal/ferroelectric/metal) structure with ferroelectric undoped-HfO 2 thin films, and successful integration is implemented for the FeFET. The appropriate O 2 vacancies ( $\text{V}_{\text {o}}^{{2}+}$ ) benefit the formation of the ferroelectric phase since they play the role of dopants and help orthorhombic phase (o-phase) formation during post-metal annealing (PMA). The $\text{V}_{\text {o}}^{{2}+}$ -rich undoped-HfO 2 FeFET exhibits a memory window (MW) of 0.5 V, ${5} \times {10}^{{4}}$ switching endurance cycles, and higher than $10^{{4}}$ sec of data retention with $\text{V}_{\text {P/E}} = \pm 5$ V.

中文翻译:

用于非易失性存储器的原子层沉积等离子体基未掺杂 HfO2 铁电 FET

展示了具有非易失性存储器特性的基于等离子体的未掺杂 HfO 2 FeFET(铁电 FET)。在等离子体增强原子层沉积 (PE-ALD) 中修改 O 2等离子体周期是增强剩余极化的有效方法。 $\text{P}_{\text {r}}$ ) 最多 2P $_{\text {r}} = 25\,\,\mu \text{C}$ /cm 2用于具有铁电未掺杂-HfO 2薄膜的MFM(金属/铁电/金属)结构 ,并且为FeFET实现了成功的集成。适当的 O 2空位 ( $\text{V}_{\text {o}}^{{2}+}$ ) 有利于铁电相的形成,因为它们在金属后退火 (PMA) 过程中起到掺杂剂的作用并有助于正交相(o 相)的形成。这 $\text{V}_{\text {o}}^{{2}+}$ -富未掺杂的 HfO 2 FeFET 具有 0.5 V 的存储窗口 (MW), ${5} \times {10}^{{4}}$ 切换耐久周期,并且高于 $10^{{4}}$ 秒的数据保留时间 $\text{V}_{\text {P/E}} = \pm 5$ 五、
更新日期:2021-07-27
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