Graphene-based materials have been extensively investigated in the energy-related applications owing to their unique properties, such as high conductivity and mechanical flexibility. Three-dimensional (3D) graphene architectures could further strengthen their performance and facilitate the applications in energy storage. To fabricate 3D graphene architectures, the rapidly developed 3D printing technology presents a lot of advantages and has received much research attention. In this paper, we reviewed the recent research advances of 3D printing of graphene-based materials and discussed the applications in energy storage areas. The main 3D printing techniques applied in constructing graphene-based structures were summarized, and the characteristics of each method were briefly introduced. The current progresses of energy storage applications, focusing on supercapacitors and energy storage batteries, were reviewed in detail. Moreover, the future research challenges and prospects were provided in the last part, aiming at stimulating more significant research and industrial applications in this subject.

石墨烯基材料由于其独特的性质，如高导电性和机械柔韧性，在能源相关应用中得到了广泛的研究。三维（3D）石墨烯架构可以进一步增强其性能并促进其在储能中的应用。为制造 3D 石墨烯架构，快速发展的 3D 打印技术呈现出许多优势，并受到了广泛的研究关注。在本文中，我们回顾了石墨烯基材料 3D 打印的最新研究进展，并讨论了其在储能领域的应用。总结了用于构建石墨烯基结构的主要3D打印技术，并简要介绍了每种方法的特点。目前储能应用的进展，重点对超级电容器和储能电池进行了详细回顾。此外，最后一部分提出了未来的研究挑战和展望，旨在激发该学科更重要的研究和工业应用。