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Geochemical Considerations from the Carboniferous Unconventional Petroleum System of SW Iberia
Minerals ( IF 2.2 ) Pub Date : 2021-07-27 , DOI: 10.3390/min11080811
Gabriel A. Barberes , Rui Pena dos Reis , Nuno L. Pimentel , André L. D. Spigolon , Paulo E. Fonseca , Przemysław Karcz , Marco C. Azevedo , Maria Teresa Barata

The Baixo Alentejo Flysch Group (BAFG) is an important stratigraphic unit that covers over half of the South Portuguese Zone (SPZ) depositional area, and it is composed by three main tectono-stratigraphic units: the Mértola, Mira, and Brejeira formations. All of these formations contain significant thicknesses of black shales and have several wide areas with 0.81 wt.%, 0.91 wt.%, and 0.72 wt.% average total organic carbon (TOC) (respectively) and thermal maturation values within gas zones (overmature). This paper is considering new data from classical methods of organic geochemistry characterization, such as TOC, Rock–Eval pyrolysis, and organic petrography, to evaluate the unconventional petroleum system from the SPZ. A total of 53 samples were collected. From the stratigraphical point of view, TOC values seem to have a random distribution. The Rock–Eval parameters point out high thermal maturation compatible with gas window (overmature zone). The samples are dominated by gas-prone extremely hydrogen-depleted type III/IV kerogen, which no longer has the potential to generate and expel hydrocarbons. The petrographic analyses positioned the thermal evolution of these samples into the end of catagenesis to metagenesis (wet to dry gas zone), with values predominantly higher than 2 %Ro (dry gas zone). The presence of thermogenic hydrocarbon fluids characterized by previous papers indicate that the BAFG from SPZ represents a senile unconventional petroleum system, working nowadays basically as a gas reservoir.

中文翻译:

伊比利亚西南石炭纪非常规石油系统的地球化学考虑

Baixo Alentejo Flysch Group (BAFG) 是一个重要的地层单元,覆盖了南葡萄牙区 (SPZ) 沉积区的一半以上,它由三个主要的构造地层单元组成:Mértola、Mira 和 Brejeira 组。所有这些地层都含有很厚的黑色页岩,并有几个宽阔的区域,平均总有机碳 (TOC) 分别为 0.81 wt.%、0.91 wt.% 和 0.72 wt.%,气层内的热成熟值(过成熟) )。本文正在考虑来自有机地球化学表征的经典方法(例如 TOC、Rock-Eval 热解和有机岩石学)的新数据,以评估 SPZ 的非常规石油系统。共收集了 53 个样品。从地层的角度来看,TOC 值似乎具有随机分布。Rock-Eval 参数指出与气体窗口(过成熟区)兼容的高热成熟度。样品主要是富含气体的极度贫氢的 III/IV 型干酪根,其不再具有生成和排出碳氢化合物的潜力。岩相分析将这些样品的热演化定位到变质作用的末期(湿气到干气区),其值主要高于 2%Ro(干气区)。先前论文所表征的热成因烃流体的存在表明,SPZ 的 BAFG 代表了一个老旧的非常规石油系统,目前基本上作为气藏工作。样品主要是富含气体的极度贫氢的 III/IV 型干酪根,其不再具有生成和排出碳氢化合物的潜力。岩相分析将这些样品的热演化定位到变质作用的末期(湿气到干气区),其值主要高于 2%Ro(干气区)。先前论文所表征的热成因烃流体的存在表明,SPZ 的 BAFG 代表了一个老旧的非常规石油系统,目前基本上作为气藏工作。样品主要是富含气体的极度贫氢的 III/IV 型干酪根,其不再具有生成和排出碳氢化合物的潜力。岩相分析将这些样品的热演化定位到变质作用的末期(湿气到干气区),其值主要高于 2%Ro(干气区)。先前论文所表征的热成因烃流体的存在表明,SPZ 的 BAFG 代表了一个老旧的非常规石油系统,目前基本上作为气藏工作。
更新日期:2021-07-27
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