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Coupling of nano-spinel MgFe2O4 on Co3O4 for heterogeneous photocatalysis and antibacterial applications: Insights of optoelectrical properties
Colloid and Interface Science Communications ( IF 4.7 ) Pub Date : 2021-07-27 , DOI: 10.1016/j.colcom.2021.100467
Asad Syed 1 , Abdallah M. Elgorban 1 , Ali H. Bahkali 1 , Nouf S.S. Zaghloul 2
Affiliation  

The binary heterojunction of MgFe2O4-Co3O4 nano-photocatalyst was constructed by sonochemical method. HRTEM represented the attachment of MgFe2O4 and Co3O4. UV–vis DRS reveals the bandgap shift (MgFe2O4 = 1.75 eV; Co3O4 = 2.35 eV) to 2.09 eV for MgFe2O4-Co3O4 that promoted white light harvesting. XPS and EDAX were performed to confirm the presence of Mg, Fe, Co and O. FTIR analysis indicates the tetrahedral and octahedral oxygen-metal peaks. The dye degradation rate of MgFe2O4-Co3O4 was boosted 7 and 11 times than MgFe2O4 and Co3O4 respectively. The MgFe2O4-Co3O4 showed excellent recycling stability and reusability. The particles found to be highly active under visible light irradiation and ·OH showed major contribution in dye degradation. The MgFe2O4-Co3O4 greatly affected the growth of Escherichia coli and Bacillus subtilis that proved its excellent antibacterial property. Therefore, MgFe2O4 decorated Co3O4 can be considered as a useful tool for multiple applications including environmental remediation by photocatalysis and as antibacterial agents.



中文翻译:

纳米尖晶石 MgFe2O4 与 Co3O4 的偶联用于异相光催化和抗菌应用:光电特性的洞察

采用声化学法构建了MgFe 2 O 4 -Co 3 O 4纳米光催化剂的二元异质结。HRTEM 表示 MgFe 2 O 4和 Co 3 O 4的附着。的UV-vis DRS揭示了带隙偏移(MgFe 2 ø 4  = 1.75电子伏特;钴3 ø 4  = 2.35电子伏特)至2.09电子伏特为MgFe 2 ö 4 -Co 3 ö 4这促进了白光收集。进行 XPS 和 EDAX 以确认 Mg、Fe、Co 和 O 的存在。FTIR 分析表明四面体和八面体氧金属峰。的染料降解速率MgFe 2 ö 4 -Co 3 ö 4被升压7个11倍,比MgFe 2 ö 4和Co 3 ö 4分别。MgFe 2 O 4 -Co 3 O 4表现出优异的循环稳定性和可重复使用性。发现在可见光照射下具有高活性的颗粒和·OH 显示出对染料降解的主要贡献。MgFe 2 O4 -Co 3 O 4极大地影响了大肠杆菌枯草芽孢杆菌的生长,证明了其优异的抗菌性能。因此,MgFe 2 O 4装饰的Co 3 O 4可以被认为是多种应用的有用工具,包括光催化环境修复和抗菌剂。

更新日期:2021-07-27
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