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Seasonal characteristics and sources of carbonaceous components and elements of PM10 (2010–2019) in Delhi, India
Journal of Atmospheric Chemistry ( IF 3.0 ) Pub Date : 2021-07-26 , DOI: 10.1007/s10874-021-09424-x
Sudhir Kumar Sharma 1, 2 , Rubiya Banoo 1, 2 , Tuhin Kumar Mandal 1, 2
Affiliation  

In this study we present the seasonal chemical characteristics and potential sources of PM10 at an urban location of Delhi, India during 2010˗2019. The concentrations of carbonaceous aerosols [organic carbon (OC), elemental carbon (EC), water soluble organic carbon (WSOC) and water insoluble organic carbon (WIOC)] and elements (Al, Fe, Ti, Cu, Zn, Mn, Pb, Cr, F, Cl, Br, P, S, K, As, Na, Mg, Ca, B, Ni, Mo, V, Sr, Zr and Rb) in PM10 were estimated to explore their possible sources. The annual average concentration (2010–2019) of PM10 was computed as 227 ± 97 µg m−3 with a range of 34˗734 µg m−3. The total carbonaceous aerosols in PM10 was accounted for 22.5% of PM10 mass concentration, whereas elements contribution to PM10 was estimated to be 17% of PM10. The statistical analysis of OC vs. EC and OC vs. WSOC of PM10 reveals their common sources (biomass burning and/or fossil fuel combustion) during all the seasons. Enrichment factors (EFs) of the elements and the relationship of Al with other crustal metals (Fe, Ca, Mg and Ti) of PM10 indicates the abundance of mineral dust over Delhi. Principal component analysis (PCA) extracted the five major sources [industrial emission (IE), biomass burning + fossil fuel combustion (BB + FFC), soil dust, vehicular emissions (VE) and sodium and magnesium salts (SMS)] of PM10 in Delhi, India. Back trajectory and cluster analysis of airmass parcel indicate that the pollutants approaching to Delhi are mainly from Pakistan, IGP region, Arabian Sea and Bay of Bengal.



中文翻译:

印度德里PM10碳质成分和元素的季节特征及来源(2010-2019年)

在这项研究中,我们介绍了2010 年和 2019 年印度德里城市的季节性化学特征和 PM 10的潜在来源。碳质气溶胶[有机碳(OC)、元素碳(EC)、水溶性有机碳(WSOC)和水不溶性有机碳(WIOC)]和元素(Al、Fe、Ti、Cu、Zn、Mn、Pb)的浓度估算了PM 10中的 Cr、F、Cl、Br、P、S、K、As、Na、Mg、Ca、B、Ni、Mo、V、Sr、Zr 和 Rb),以探索其可能的来源。 PM 10年平均浓度(2010-2019 年)计算为 227 ± 97 µg m −3,范围为 34˗734 µg m −3。 PM 10中的总碳质气溶胶占 PM 10质量浓度的 22.5%,而元素对 PM 10的贡献估计为 PM 10的 17% 。 PM 10的 OCEC 和 OCWSOC的统计分析揭示了它们在所有季节的共同来源(生物质燃烧和/或化石燃料燃烧)。 PM 10的元素富集因子 (EF) 以及 Al 与其他地壳金属(Fe、Ca、Mg 和 Ti)的关系表明德里上空矿物尘埃的丰度。主成分分析(PCA)提取PM 10的5个主要来源【工业排放(IE)、生物质燃烧+化石燃料燃烧(BB+FFC)、土壤扬尘、车辆排放(VE)和钠镁盐(SMS)】在印度德里。气团回溯轨迹和聚类分析表明,接近德里的污染物主要来自巴基斯坦、IGP地区、阿拉伯海和孟加拉湾。

更新日期:2021-07-26
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