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Cooperative Photocatalysis with 4-Amino-TEMPO for Selective Aerobic Oxidation of Amines over TiO2 Nanotubes
Chemistry - An Asian Journal ( IF 4.1 ) Pub Date : 2021-07-23 , DOI: 10.1002/asia.202100682
Yuexin Wang 1 , Jun Zhou 1 , Xiaoming Ma 1 , Xia Li 1 , Xianjun Lang 1
Affiliation  

Sodium 6,7-dihydroxynaphthalene-2-sulfonate (DHNS) is obtained by extending the π-conjugated system of catechol by a benzene ring and adding a substituent sodium sulfonate (−SO3Na+). Cooperative photocatalysis of DHNS−TiO2 nanotubes with 4-amino-TEMPO shows the best activity towards the blue light-induced selective aerobic oxidation of benzylamine to N-benzylidenebenzylamine.
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中文翻译:

4-氨基-TEMPO协同光催化在TiO2纳米管上选择性好氧氧化胺

6,7-二羟基萘-2-磺酸钠(DHNS)是通过苯环扩展邻苯二酚的π-共轭体系并添加取代基磺酸钠(-SO 3 - Na +)而获得的。DHNS-TiO 2纳米管与4-氨基-TEMPO 的协同光催化对蓝光诱导的苄胺选择性有氧氧化为N-亚苄基苄胺显示出最佳活性。
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更新日期:2021-09-20
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