Chirality induction to achiral molecules by silica-coated chiral molecular assemblies,Chirality

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Chirality induction to achiral molecules by silica-coated chiral molecular assemblies
Chirality ( IF 2.8 ) Pub Date : 2021-07-23 , DOI: 10.1002/chir.23339
Antoine Scalabre ₁ , Yutaka Okazaki ₂ , Balamurugan Kuppan ₁ , Thierry Buffeteau ₃ , Fabrizio Caroleo ₄ , Gabriele Magna ₄ , Donato Monti ₄ , Roberto Paolesse ₄ , Manuela Stefanelli ₄ , Sylvain Nlate ₁ , Emilie Pouget ₁ , Hirotaka Ihara ₅ , Dario M Bassani ₃ , Reiko Oda ₁

Affiliation

Hybrid silica-organic nanohelices are used to organize a large variety of nonchiral small organic molecules or inorganic anions to nanometer-sized assemblies. Such chiral organization of achiral molecules induces chiroptical properties as detected by vibrational or electronic circular dichroism (CD), as well as from circularly polarized luminescence (CPL).

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