当前位置: X-MOL 学术Vacuum › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Improving the tribological and anti-corrosion property of the WS2 film through Ta doping
Vacuum ( IF 4 ) Pub Date : 2021-07-22 , DOI: 10.1016/j.vacuum.2021.110485
Jun Yang 1 , Desheng Wang 1 , Yanlong Fu 1 , Qinqin Wang 1 , Ming Hu 1 , Dong Jiang 1 , Xiaoming Gao 1 , Jiayi Sun 1 , Lijun Weng 1
Affiliation  

The easy oxidation and poor corrosion resistance of the sputtered WS2 film would limit its application in spacecraft due to the sharp deterioration of lubricity resulting from the contact with the marine atmosphere inevitably with the increasing space launch from sea or seaside. In this study, the active metal Ta was skillfully introduced into the WS2 film through co-sputtering of the WS2 and Ta targets. The influence of the doped Ta related microstructure regulation on the tribological and anti-corrosion properties of the prepared composite films was investigated. It showed that the incorporation of the active Ta would activate the residual O atoms to form Ta2O5 phase while making the WS2 phase partly oxidized to form the WSxOy and WO3. WS2–Ta composite films with low Ta content exhibited low friction coefficient and long wear life more than 3 times of that for pure WS2 film. In addition, the corrosion resistance of WS2–Ta film was improved by a positive shift of corrosion potential in salt spray with increasing the Ta content, originating from the passivation effect of the Ta2O5 phase and the WSxOy phase in the film as well as the dense structure.



中文翻译:

Ta掺杂提高WS 2薄膜的摩擦学和抗腐蚀性能

溅射的WS 2薄膜易氧化、耐腐蚀性能差,随着越来越多的海上或海边空间发射,不可避免地与海洋大气接触导致润滑性急剧恶化,从而限制了其在航天器中的应用。在本研究中,通过 WS 2和 Ta 靶的共溅射,将活性金属 Ta 巧妙地引入到 WS 2薄膜中。研究了掺杂 Ta 相关的微观结构调节对制备的复合膜的摩擦学和抗腐蚀性能的影响。结果表明,活性 Ta 的掺入会激活残留的 O 原子形成 Ta 2 O 5相,同时使 WS 2相部分氧化形成WS x O y和WO 3。低Ta含量的WS 2 -Ta复合薄膜摩擦系数低,磨损寿命长,是纯WS 2薄膜的3倍以上。此外,由于Ta 2 O 5相和WS x O y相的钝化作用,随着Ta含量的增加,WS 2 -Ta膜的耐腐蚀性能通过盐雾腐蚀电位的正移而提高。薄膜以及致密的结构。

更新日期:2021-07-24
down
wechat
bug