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Strong energy transfer induced deep-red emission for LED plant growth phosphor (Y,Ba)3(Al,Si)5O12: Ce3+, Cr3+
Journal of Luminescence ( IF 3.3 ) Pub Date : 2021-07-22 , DOI: 10.1016/j.jlumin.2021.118352
Mengwen Yan 1 , Takatoshi Seto 1 , Yuhua Wang 1
Affiliation  

A new phosphor Y2BaAl4SiO12: Ce3+, Cr3+ yielding much efficient energy transfer from Ce3+ to Cr3+ and strongly emitting deep-far red emission under blue LED excitation has been reported. The doping of Ce3+ into Y2BaAl4SiO12: Cr3+ has greatly enhanced the excitation at blue region with increasing deep-far red emission more than three times. It is highly noticeable that an efficient energy transfer has assisted in the enhancement of the excitation for deep-far red emission illustrated through a stronger 4f→5d transition of Ce3+ than parity-forbidden 4A24T1 transition of Cr3+. The yellow emission of Ce3+ was almost completely depressed to nearly zero during the energy transition. The mechanism was considered as dipole-dipole interaction through the decay curve of the yellow emission, where the generation of a strong energy transfer in widely distributed Ce3+ and Cr3+ activators was proceeded through this interaction. It can intensively contribute to a new type of LED plant growth with inducing morphosis of plants under far red light.



中文翻译:

LED 植物生长荧光粉 (Y,Ba)3(Al,Si)5O12: Ce3+, Cr3+ 的强能量转移诱导深红色发射

一种新型荧光粉 Y 2 BaAl 4 SiO 12 : Ce 3+ , Cr 3+产生了从 Ce 3+到 Cr 3+ 的高效能量转移,并在蓝光 LED 激发下强烈发射深远红光。Ce 3+掺杂到Y 2 BaAl 4 SiO 12 : Cr 3+大大增强了蓝色区域的激发,使深远红光发射增加了三倍以上。值得注意的是,有效的能量转移有助于增强深远红光发射的激发,这通过 Ce 更强的 4f→5d 跃迁来说明3+比奇偶禁止4 A 24 T 1 Cr 3+ 的转变。在能量转换过程中,Ce 3+的黄色发射几乎完全抑制到接近零。该机制被认为是通过黄色发射的衰减曲线的偶极-偶极相互作用,其中通过这种相互作用在广泛分布的Ce 3+和Cr 3+活化剂中产生强能量转移。它可以在远红光下诱导植物形态变化,为新型LED植物生长做出贡献。

更新日期:2021-07-27
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