Renewable energy has gained much attention in recent decades because of the global concerns related to the search for abundant, ecofriendly, and durable batteries and their potential to substitute traditional energy sources. Compared with lithium-based batteries, the sodium-ion batteries (SIBs) and potassium-ion batteries (PIBs) have high promise for next-generation battery systems due to their earth abundance, suitable working potential, and high capacity. Some important breakthroughs have been reported recently for sodium-ion batteries (SIBs) and potassium-ion batteries (PIBs), such as enhancement of electrochemical performances due to size effect, high stability, and excellent conductivity, however it is still imperative to explore anode materials that exhibits ultra-long lifetime and high energy density. Herein, we review the recent progress on the bismuth-based anode materials because they demonstrate a comparable higher theoretical specific capacity and emerge as promising electrode materials for sodium and potassium ion batteries. The structural features and synthetic strategies of bismuth-based anodes in the field of rechargeable K/Na ion batteries are summarized, and their existing challenges for battery development and potential solution for perspective of future research are outlined.

近几十年来，可再生能源备受关注，因为全球都在关注寻找丰富、环保和耐用的电池及其替代传统能源的潜力。与锂基电池相比，钠离子电池（SIBs）和钾离子电池（PIBs）由于其地球资源丰富、合适的工作电位和高容量，在下一代电池系统中具有广阔的前景。最近，钠离子电池（SIBs）和钾离子电池（PIBs）取得了一些重要的突破，例如由于尺寸效应而提高电化学性能、高稳定性和优异的导电性，但仍然需要探索负极具有超长寿命和高能量密度的材料。在此处，我们回顾了铋基负极材料的最新进展，因为它们表现出相当高的理论比容量，并成为钠和钾离子电池的有前途的电极材料。总结了可充电钾/钠离子电池领域中铋基负极的结构特征和合成策略，概述了它们对电池发展的现有挑战和未来研究的潜在解决方案。