Alkyne Surrogates in Cycloaddition Reactions for the Preparation of Molecules of Interest,Asian Journal of Organic Chemistry

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Alkyne Surrogates in Cycloaddition Reactions for the Preparation of Molecules of Interest
Asian Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2021-07-20 , DOI: 10.1002/ajoc.202100345
Muriel Amatore ₁ , Jean‐Luc Parrain ₁ , Laurent Commeiras ₁

Affiliation

Although alkynes are very good partners for cycloaddition reactions, their use is often associated to several drawbacks, such as multi-steps synthesis, selectivity and stability issues or difficulty to handle for alkynes with low boiling point. In this context, alkyne surrogates have emerged as alternative substitution partners unlocking new opportunities. This review intends to highlight the outstanding power and utility of such compounds for the preparation of high value molecules.