A spherical Ag^I₄₆S₁₃ cluster surrounded by 14 fac-[Ir(2-aminoethanethiolato)₃] was newly synthesized and structurally characterized. The cluster reacted with Cu^I and Au^I to afford Ag₄₃Cu₃S₁₃ and Ag₄₃Au₃S₁₃ clusters with retention of its overall structure, accompanied by a change in its photophysical properties.

中文翻译：

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八面体铱（III）硫醇盐保护的光致发光银（I）硫化物纳米团簇的杂金属化

由 14 fac -[Ir(2-aminoethanethiolato) ₃ ]包围的球形 Ag ^I ₄₆ S ₁₃簇 是新合成的，并对其进行了结构表征。该簇与Cu ^I和Au ^I反应得到Ag ₄₃ Cu ₃ S ₁₃和Ag ₄₃ Au ₃ S ₁₃簇，并保留其整体结构，并伴随其光物理性质的变化。