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Influences of Si content on the high-temperature oxidation behavior of X10CrAlSi18 ferritic heat-resistant stainless steel at 700 °C and 800 °C
Surface & Coatings Technology ( IF 5.3 ) Pub Date : 2021-07-17 , DOI: 10.1016/j.surfcoat.2021.127523
Yingbo Zhang 1, 2 , Dening Zou 1 , Xiaoqiao Wang 2 , Quansheng Wang 2 , Ran Xu 2 , Wei Zhang 3
Affiliation  

X10CrAlSi18 FHSS (ferritic heat-resistant stainless steel) has received a lot of attention due to its advantageous combination of creep resistance and oxidation resistance. The influence of Si content on the high-temperature oxidation resistance of X10CrAlSi18 FHSS after oxidation at 700 and 800 °C for up to 180 h in air was investigated in this study. According to the results, a higher Si content could coarsen the grain of ferrite and simultaneously increased the amount of (Cr, Fe)23C6 carbides, which caused cracks and reduced the adhesion between the oxide film and the matrix. After oxidation at 700 °C, the oxide film of 0.77Si FHSS and 1.35Si FHSS were found to be primarily composed of Al2O3, SiO2, Cr2O3, Fe2O3, Mn2O3 and MnCr2O4, with thickness of 5.10 μm and 5.56 μm, respectively. The oxide films formed at 800 °C were primarily composed of Al2O3, SiO2, Cr2O3, FeCr2O4, Mn2O3 and MnCr2O4 with thickness of 5.55 μm and 7.37 μm, respectively. A higher Si content was discovered to increase the amount of MnCr2O4 in the outer layer of the oxide film, which resulted in a looser spinel structure and reduced the oxidation resistance of X10CrAlSi18 FHSS.



中文翻译:

Si含量对X10CrAlSi18铁素体耐热不锈钢700℃和800℃高温氧化行为的影响

X10CrAlSi18 FHSS(铁素体耐热不锈钢)因其抗蠕变性和抗氧化性的优势组合而受到广泛关注。本研究研究了 Si 含量对 X10CrAlSi18 FHSS 在 700 和 800 °C 下在空气中氧化长达 180 小时后的高温抗氧化性的影响。结果表明,较高的Si含量会使铁素体晶粒粗化,同时增加(Cr,Fe) 23 C 6碳化物的含量,从而引起裂纹并降低氧化膜与基体之间的附着力。在 700 °C 氧化后,发现 0.77Si FHSS 和 1.35Si FHSS 的氧化膜主要由 Al 2 O 3、SiO 2、Cr 组成2 O 3、Fe 2 O 3、Mn 2 O 3和MnCr 2 O 4,厚度分别为5.10μm和5.56μm。800℃下形成的氧化膜主要由Al 2 O 3、SiO 2、Cr 2 O 3、FeCr 2 O 4、Mn 2 O 3和MnCr 2 O 4 组成,厚度分别为5.55μm和7.37μm。发现较高的 Si 含量会增加 MnCr 2 O 4的量 X10CrAlSi18 FHSS 的外层氧化膜,导致尖晶石结构松散,降低抗氧化性能。

更新日期:2021-07-20
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