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Photostable Luminescent Triarylmethyl Radicals and Their Metal Complexes: Photofunctions Unique to Open-shell Electronic States
Chemistry Letters ( IF 1.4 ) Pub Date : 2021-07-16 , DOI: 10.1246/cl.210201
Tetsuro Kusamoto 1, 2, 3 , Shun Kimura 1, 4
Affiliation  

Stable organic radicals with unpaired electrons exhibit vivid physical characteristics such as magnetic and electron-conducting properties, while being assumed as non-emissive chemical species. This highlight review introduces the luminescence properties of radicals and radical-ligated metal complexes as emerging functions of open-shell molecular systems. Their unique photofunctions will expand the utility of radicals in molecular photonics.

中文翻译:

光稳定的发光三芳基甲基自由基及其金属配合物:开壳电子态独有的光功能

具有不成对电子的稳定有机自由基表现出生动的物理特性,如磁性和电子传导特性,同时被假定为非发射化学物质。这篇重点综述介绍了自由基和自由基连接的金属配合物作为开壳分子系统的新兴功能的发光特性。它们独特的光功能将扩大自由基在分子光子学中的应用。
更新日期:2021-07-16
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