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Phase distribution of uranium in matrices obtained by co-melting basalt and uranium-containing aluminum oxide
Annals of Nuclear Energy ( IF 1.9 ) Pub Date : 2021-07-16 , DOI: 10.1016/j.anucene.2021.108555
K.V. Martynov 1 , V.V. Kulemin 1 , M.P. Gorbacheva 1 , S.A. Kulyukhin 1
Affiliation  

Safe disposal of nuclear waste is key to sustainable use of nuclear energy. Exploring safe and reliable disposal methods for nuclear waste has become a research hotspot. The phase distribution of uranium in matrices obtained by co-melting basalt and uranium-containing Al2O3 was examined for the development of a potential material for radioactive waste immobilization. The co-melting of basalt with UO3-containing Al2O3 produced matrices containing glass, plagioclase, and spinel as major phases. The highest uranium content (97 mass % UO3) was observed on the non-dissolved fragment of the Al2O3 grains. The titanium-containing complex oxide phase, supposedly, ilmenite, contained up to 62 mass % UO3. The glass phase exhibited an uneven distribution of uranium, with its content ranging ~ 5 to ~ 10 mass % UO3. Data on the leaching of uranium into H2O from the co-melt of basalt and UO3-containing Al2O3 were obtained.



中文翻译:

玄武岩与含铀氧化铝共熔所得基质中铀的相分布

核废料的安全处置是核能可持续利用的关键。探索安全可靠的核废料处置方法已成为研究热点。检查了通过共熔玄武岩和含铀的 Al 2 O 3获得的基质中铀的相分布,以开发用于放射性废物固定的潜在材料。玄武岩与含UO 3的Al 2 O 3的共熔产生含有玻璃、斜长石和尖晶石作为主要相的基质。在 Al 2 O 3的未溶解碎片上观察到最高的铀含量 (97 质量 % UO 3 )谷物。含钛复合氧化物相,推测为钛铁矿,含有高达62质量%的UO 3。玻璃相表现出铀的不均匀分布,其含量范围为~5 至~10 质量% UO 3。获得了铀从玄武岩和含UO 3的 Al 2 O 3的共熔体中浸出到 H 2 O 中的数据。

更新日期:2021-07-16
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