Journal of Luminescence ( IF 3.6 ) Pub Date : 2021-07-16 , DOI: 10.1016/j.jlumin.2021.118337 Jingcheng Feng 1, 2 , Heng Tu 1, 2 , Guochun Zhang 1, 2, 3
Tm3+-doped La2CaB10O19 (Tm3+: LCB) crystal with dimensions of 40 × 16 × 14 mm3 has been grown by the top-seeded solution growth (TSSG) method. At room temperature, the absorption spectrum in the wavelength range of 190–2000 nm and emission spectrum under the excitation of 466 nm were measured by using () oriented crystal wafers. According to the Judd−Ofelt theory, the fundamental spectral parameters were calculated, including phenomenological intensity parameters (t = 2, 4, 6), transition probability A, emission cross sections σem, fluorescence branch ratio βc, and radioactive lifetime τrad. Tm3+: LCB crystal may be a potential near infrared laser material under the excitation of 466 nm which is closed to the wavelength of GaN laser diode.
中文翻译:
Tm 3+掺杂的La 2 CaB 10 O 19晶体的生长和光谱特性
尺寸为 40 × 16 × 14 mm 3 的Tm 3+掺杂的 La 2 CaB 10 O 19 (Tm 3+ : LCB) 晶体已通过顶部种子溶液生长 (TSSG) 方法生长。在室温下,190-2000 nm波长范围内的吸收光谱和466 nm激发下的发射光谱通过使用() 定向晶体晶片。根据 Judd-Ofelt 理论,计算了基本的光谱参数,包括现象学强度参数 (t = 2, 4, 6)、跃迁概率A、发射截面σ em、荧光分支比β c和放射性寿命τ rad。Tm 3+ : LCB晶体在接近GaN激光二极管波长的466nm激发下可能是一种潜在的近红外激光材料。