Journal of Industrial and Engineering Chemistry ( IF 5.9 ) Pub Date : 2021-07-14 , DOI: 10.1016/j.jiec.2021.07.010 Junmo Jeon 1 , Minsik Choi 2, 3 , Seul Bi Kim 4 , Tae Hoon Seo 5 , Bon-Cheol Ku 2 , Seongwoo Ryu 3 , Ji Hun Park 4 , Young-Kwan Kim 1
This paper demonstrates eggshell membrane protein hydrolysate (ESMH), a critical food waste worldwide, can be harnessed as a multifunctional agent for eco-friendly reduction and functionalization of graphene oxide (GO) based on its diverse and abundant functional groups. The resulting GO reduced and functionalized with ESMH (ESMH-RGO) exhibits an aqueous dispersibility and applicability as a 2-dimensional support for synthesis of catalytic Au nanoparticles (Au NPs) with a high density. The AuNPs synthesized on ESMH-RGO (AuNPs@ESMH-RGO) presents a high catalytic activity for conversion of environmental pollutant (4-nitrophenol) to an industrially useful raw material (4-aminophenol). Those results clearly indicate that ESMH has a strong potential in environmental and materials chemistry.
中文翻译:
蛋壳膜水解物作为多功能试剂用于合成功能化石墨烯类似物及其催化纳米复合材料
本文论证了蛋壳膜蛋白水解物 (ESMH) 是一种全球重要的食物垃圾,基于其多样化和丰富的官能团,可用作多功能剂,对氧化石墨烯 (GO) 进行环保还原和功能化。所得的用 ESMH 还原和功能化的 GO(ESMH-RGO)表现出水分散性和适用性,作为合成高密度催化金纳米粒子(Au NPs)的二维载体。在 ESMH-RGO (AuNPs@ESMH-RGO) 上合成的 AuNPs 具有将环境污染物(4-硝基苯酚)转化为工业上有用的原料(4-氨基苯酚)的高催化活性。这些结果清楚地表明 ESMH 在环境和材料化学方面具有强大的潜力。