Reaction of 6,7-bis(chloromethyl)-1,2,3,4-tetrahydronaphthalene with tellurium powder and potassium iodide in 2-butoxyethanol gave 2,2-diiodo-1,3,5,6,7,8-hexahydro-naphtho[2,3-c]tellurophene(1) as a red-orange solid in 40% yield. Reduction of 1 with hydrazine hydrate gave a pale yellow solid of 1,3,5,6,7,8-hexahydronaphtho[2,3-c]telluro-phene(2) in 80% yield. Chlorination, bromination of 2 and its reaction with benzyl bromide and N-bromosuccinimide were reported. 2,2-Bis(dimethyldithiocarbamato)-, 2,2-bis (diethyldithiocarbamato)- and 2,2-bis(piperidine-1-carbodithioate)-1,3,5,6,7,8-hexahydro-naphtho[2,3-c]tellurophene were prepared by the reaction of the corresponding sodium dithiocarbamate salt with 1. Mononuclear platinum complex (ie, [(C12H14Te)2PtCl2]) was obtained by the reaction of 2 with K2PtCl4. Reaction of 6,7-bis(chloromethyl)-1,2,3,4-tetrahydronaphthalene with KTeCN in DMSO solution gave 2,2-dihydroxo-1,3,5,6,7,8-hexahydronaphtho[2,3-c]tellurophene (11) as a white solid in 55% yield. All these new compounds were characterized by elemental analysis, IR, 1H, and 13C NMR, and mass spectroscopic data.

中文翻译：

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一种新的环状碲化物。1,3,5,6,7,8-六氢萘[2,3-c]碲苯的合成与反应

6,7-双(氯甲基)-1,2,3,4-四氢萘与碲粉和碘化钾在2-丁氧基乙醇中反应得到2,2-二碘-1,3,5,6,7,8-六氢-naphtho[2,3-c]tellurophene(1) 为红橙色固体，产率为 40%。用水合肼还原 1 得到 1,3,5,6,7,8-六氢萘并 [2,3-c] 碲-苯 (2) 的淡黄色固体，产率为 80%。报道了 2 的氯化、溴化及其与苄基溴和 N-溴代琥珀酰亚胺的反应。2,2-双(二甲基二硫代氨基甲酸)-、2,2-双(二乙基二硫代氨基甲酸)-和2,2-双(哌啶-1-碳二硫代)-1,3,5,6,7,8-六氢萘[2 ,3-c] 碲酚通过相应的二硫代氨基甲酸钠盐与 1 的反应制备。单核铂络合物（即，[(C12H14Te)2PtCl2]）通过 2 与 K2PtCl4 的反应获得。6,7-双(氯甲基)-1,2,3的反应，4-四氢萘与 KTeCN 在 DMSO 溶液中得到 2,2-二羟基-1,3,5,6,7,8-六氢萘并[2,3-c]碲苯 (11)，为白色固体，产率为 55%。所有这些新化合物均通过元素分析、IR、1H 和 13C NMR 以及质谱数据进行表征。