Physics of Wave Phenomena ( IF 1.1 ) Pub Date : 2021-07-13 , DOI: 10.3103/s1541308x21020059 V. I. Bruskov 1 , E. E. Karmanova 1 , A. V. Chernikov 1 , A. M. Usacheva 1 , V. E. Ivanov 1 , V. I. Emel’yanenko 1
Abstract—
Formation of hydrated electrons in water exposed to thermal electromagnetic radiation and influence of temperature (9–75°С) and D2O concentration (0–100 vol %) on their optical absorption spectra are investigated. Two distinct bands at 738 and 836 nm are observed in the initial spectrum. The spectra at temperatures from 10 to 80°С have two isosbestic points and four Gaussian components with domination of the component at 720 nm. As temperature rises, absorption increases and bands shift to the short-wave region. As the D2O concentration increases, the absorption spectrum intensity considerably decreases to its complete disappearance in 100% heavy-hydrogen water.
中文翻译:
热电磁暴露下水中水合电子的形成
摘要-
研究了暴露于热电磁辐射的水中水合电子的形成以及温度 (9–75°С) 和 D 2 O 浓度 (0–100 vol%) 对其光学吸收光谱的影响。在初始光谱中观察到 738 和 836 nm 处的两个不同波段。在 10 到 80°С 温度下的光谱有两个等吸收点和四个高斯分量,其中分量在 720 nm 处占主导地位。随着温度升高,吸收增加并且谱带移动到短波区域。随着 D 2 O 浓度的增加,吸收光谱强度显着降低,在 100% 重氢水中完全消失。