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Nano-encapsulated solvent via pickering emulsion in NaOH aqueous solution for indoor CO2 capture
Journal of CO2 Utilization ( IF 7.2 ) Pub Date : 2021-07-10 , DOI: 10.1016/j.jcou.2021.101637
Seonggon Kim 1 , Minjae Kim 1 , Ronghuan Xu 1 , Jong Ha Park 1 , Jae Won Lee 1 , Yong Tae Kang 1
Affiliation  

Considering the limitations of indoor ventilation owing to air pollution, CO2 concentration rises rapidly to 3000 ppm, which is a level that can affect human health. It is essential to develop materials to reduce naturally occurring CO2 in the buildings. Herein, a nano-encapsulated solvent (NES) via Pickering emulsion is proposed for indoor CO2 capture. NaOH aqueous solution is wrapped with hydrophobic surface-functionalized SiO2 (HS-SiO2) nanoparticles, and the corrosiveness of NaOH is not caused by HS-SiO2 wall. CO2 capture capacity of NES-NaOH is evaluated as 7.57 mmol-CO2/g-solvent which is the highest compared to other solvents including metal-organic frameworks (MOFs); it exhibits excellent structural stability in terms of temperature, time, moisture, and CO2 reaction. NES-NaOH presents high selectivity toward CO2 molecules due to the characteristics of NaOH with high gas permeability of macroporous silica wall and it is dispersed in a silicone oil harmless to human body. It is concluded that NES-NaOH can be successfully applied to air purifier filter to control the CO2 concentration in buildings.



中文翻译:

NaOH水溶液中通过pickering乳液的纳米包封溶剂用于室内CO 2捕获

考虑到空气污染对室内通风的限制,CO 2浓度迅速上升到3000 ppm,这是一个可以影响人体健康的水平。开发材料以减少建筑物中自然产生的 CO 2是必不可少的。在此,提出了一种通过 Pickering 乳液的纳米封装溶剂 (NES) 用于室内 CO 2捕获。NaOH水溶液被疏水表面功能化的SiO 2 (HS-SiO 2 )纳米颗粒包裹,NaOH的腐蚀性不是由HS-SiO 2壁引起的。NES-NaOH 的CO 2捕获能力评估为 7.57 mmol-CO 2/g-溶剂,与包括金属有机骨架 (MOF) 在内的其他溶剂相比最高;它在温度、时间、水分和 CO 2反应方面表现出优异的结构稳定性。NES-NaOH由于NaOH具有大孔二氧化硅壁的高透气性的特性,并且分散在对人体无害的硅油中,因此对CO 2分子具有高选择性。结论是NES-NaOH可以成功地应用于空气净化器过滤器以控制建筑物中的CO 2浓度。

更新日期:2021-07-12
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