Taming Electron Transfers: From Breaking Bonds to Creating Molecules,The Chemical Record

当前位置： X-MOL 学术 › Chem. Rec. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Taming Electron Transfers: From Breaking Bonds to Creating Molecules
The Chemical Record ( IF 7.0 ) Pub Date : 2021-07-07 , DOI: 10.1002/tcr.202100151
Niklas von Wolff ₁ , Marc Robert _{1,

2}

Affiliation

The electron is the ultimate redox reagent to build and reshape molecular structures. Understanding and controlling the parameters underlying dissociative electron transfer (DET) reactivity and its coupling with proton transfer is crucial for combining selectivity, kinetics and energy efficiency in molecular chemistry. Reactivity understanding and mechanistic elements in DET processes are traced back and key examples of current research efforts are presented, demonstrating a large variety of applications. The involvement of DET pathways indeed encompasses a broad range of processes such as photoredox catalysis, CO₂ reduction and alcohol oxidation. Interplay between these experimental examples and fundamental mechanistic study provides a powerful path to the understanding of driving force-rate relationships, which is crucial for the development of future generations of energy efficient catalytic schemes in redox organic chemistry.

中文翻译：

驯服电子转移：从破坏键到创建分子

电子是构建和重塑分子结构的终极氧化还原试剂。了解和控制离解电子转移 (DET) 反应性及其与质子转移的耦合的参数对于结合分子化学中的选择性、动力学和能量效率至关重要。追溯了 DET 过程中的反应性理解和机械要素，并介绍了当前研究工作的关键示例，展示了各种各样的应用。DET 途径的参与确实涵盖了广泛的过程，例如光氧化还原催化、CO ₂还原和酒精氧化。这些实验实例与基本机理研究之间的相互作用为理解驱动力-速率关系提供了一条强有力的途径，这对于开发下一代氧化还原有机化学节能催化方案至关重要。

更新日期：2021-07-07

点击分享查看原文

点击收藏

阅读更多本刊最新论文