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Photocatalytic CO2 reduction with new band gap energy evaluation from spectroscopic relationship of graphene-Mg2CuSnCoO6 composite bridged with organics
Physica E: Low-dimensional Systems and Nanostructures ( IF 3.3 ) Pub Date : 2021-07-06 , DOI: 10.1016/j.physe.2021.114864
Won-Chun Oh 1, 2 , Yonrapach Areerob 2, 3
Affiliation  

A new structure of graphene-Mg2CuSnCoO6 composite bridged with gallic acid (GMG) was synthesized with a novel method. Band gap energy of the newly synthesized nanocomposite was evaluated with a laser-wavelength region and DRS method. Evaluation and analysis were based on the relationship among XRD, HRTEM, XPS, Raman scattering, and computer simulated model structure. Changes in the structure of graphene or graphene-based composite were associated with location changes of the valence band and the conduction band. Electron density was used to confirm the number of electrons by computer simulation. Finally, such graphene-Mg2CuSnCoO6-gallic acid nanocomposite was used for photocatalytic CO2 reduction into methanol. Under UV-light irradiation, the highest methanol yield was 5.576% with 0.6 g of scavenger. This work might offer a promising strategy for measuring band gap energies of different types of semiconductors.



中文翻译:

从与有机物桥接的石墨烯-Mg 2 CuSnCoO 6复合材料的光谱关系评估光催化CO 2还原和新的带隙能量

用一种新方法合成了一种新结构的石墨烯-Mg 2 CuSnCoO 6复合物与没食子酸(GMG)桥接。使用激光波长区域和 DRS 方法评估新合成的纳米复合材料的带隙能量。评价和分析基于XRD、HRTEM、XPS、拉曼散射和计算机模拟模型结构之间的关系。石墨烯或石墨烯基复合材料结构的变化与价带和导带的位置变化有关。电子密度用于通过计算机模拟确认电子数。最后,这种石墨烯-Mg 2 CuSnCoO 6 -没食子酸纳米复合材料用于光催化CO 2还原成甲醇。在紫外光照射下,0.6 g清除剂的甲醇产率最高为5.576%。这项工作可能为测量不同类型半导体的带隙能量提供了一种有前景的策略。

更新日期:2021-07-12
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