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Superparamagnetic cobalt ferric nanoparticles incorporated biopolymers extracted from dragon fruit (hylocereus undatus) peels for nickel(II) removal
Environmental Technology & Innovation ( IF 6.7 ) Pub Date : 2021-07-03 , DOI: 10.1016/j.eti.2021.101773
Nghia T. Bui 1 , Vinh H. Nguyen 1 , Dao T. Le 1 , Thi Tuong Van Tran 1 , Trung Huu Bui 2
Affiliation  

Low-cost adsorbents derived from agricultural by-products incorporated magnetic nanoparticles (NPs) are promising and novel adsorbents for water/wastewater treatment due to their outstanding performance and easy separation. This study reports a nanocomposite of cobalt superparamagnetic (CoFe 2O4) NPs incorporated biopolymers extracted from a dragon fruit (hylocereus undatus) peel, called bp-CoFe 2O4, to potentially remove Ni(II) ions from aqueous solutions. Morphologic and structural properties of the bp-CoFe 2O4 were successfully characterized using a scanning electron spectrometry, X-ray diffraction, Fourier transform infrared spectrometry, and vibrating sample magnetometer (VSM). The bp-CoFe 2O4 particles exhibited soft and superparamagnetic properties, which can be easily recycled using an external magnet. Ni(II) adsorption on the bp-CoFe2O4 was attributed to both the components including CoFe2O4 particles and coated biopolymers. Indeed, the bp-CoFe2O4 adsorbing Ni(II) ions reached optimal at pH 6 (88% of Ni(II) removal at an adsorbent dose of 1 g/L and Ni(II) concentration of 171.1 mg/L). The bp-CoFe 2O4 can maintain the effective treatment of Ni(II) ion (only 10% of efficiency loss) up to three cycles of the regeneration. Owing to retaining the magnetic property through the regeneration cycles, this bio-adsorbent would promise a high potential for long-term treatment of Ni(II) ions from polluted waters with easy separation.



中文翻译:

超顺磁性钴铁纳米粒子结合从火龙果(火龙果)果皮中提取的生物聚合物,用于去除镍(II)

源自农业副产品的低成本吸附剂结合了磁性纳米粒子 (NPs),由于其优异的性能和易于分离,因此是用于水/废水处理的有前途的新型吸附剂。这项研究报告了钴超顺磁性 (CoFe 2 O 4 ) NPs纳米复合材料从火龙果 ( hylocereus undatus ) 果皮中提取的生物聚合物,称为 bp-CoFe 2 O 4,有可能从水溶液中去除 Ni(II) 离子。bp-CoFe 2 O 4 的形态和结构特性使用扫描电子能谱、X 射线衍射、傅里叶变换红外光谱和振动样品磁强计 (VSM) 成功表征。bp-CoFe 2 O 4颗粒表现出柔软和超顺磁性的特性,可以使用外部磁铁轻松回收。Ni(II)在bp-CoFe 2 O 4上的吸附归因于包括CoFe 2 O 4颗粒和涂覆的生物聚合物的两种组分。事实上,bp-CoFe 2 O 4吸附 Ni(II) 离子在 pH 值下达到最佳6 (在 1 g/L 的吸附剂剂量和 171.1 mg/L 的 Ni(II) 浓度下,88% 的 Ni(II) 去除率。bp-CoFe 2 O 4可以保持对 Ni(II) 离子的有效处理(仅10% 的效率损失)最多三个循环的再生。由于通过再生循环保持磁性,这种生物吸附剂有望长期处理污染水中的 Ni(II) 离子,并且易于分离。

更新日期:2021-07-04
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