Some medieval ceramic finds obtained from Zeytinli Island (Erdek, Turkey) excavations were examined using archeometry techniques. First of all, the color values of the ceramics samples, which were coded and photographed, were determined using the Munsell color system. Morphological structures, chemical and mineralogical contents of the samples were determined by Scanning Electron Microscope/ Energy Dispersive X-ray (SEM/EDX), Wavelength Dispersive X-Ray Fluorescence (WD-XRF) and X-ray Diffraction Method (XRD) analysis. Information was obtained about the matrix, mineral phases, particle sizes, aggregate content, and porosity of ceramics by elemental and color analysis by observations SEM, XRD and XRF measurements. Quartz, Vermiculite, Sepiolite, Illite, Calcite, Hematite mineral phases were found in AD 6th and 7th century ceramic samples (S1, S2, S3) by evaluating the obtained XRD measurements. In addition to other phases, Berlinite, Caracolite and Enstatite phases were observed in AD 13th century ceramics. In the ceramics samples, O, Mg, Al, Si and Ca elements were found in major amounts. SiO₂ and Al₂O₃ compounds were found to have varying concentrations of 67.37-52.95% and 34.39-15.65%, respectively. The elements such as Cu, Sr, Rb, Ni and Mn were observed in trace amounts. Pb element was found in the glazes of the studied ceramics excavated from the Eastern Church. SEM-EDX analysis revealed that the surfaces of well-fired ceramics samples possess a homogeneous structure. According to the results of WD-XRF analysis, it was seen that the chemical compositions and production techniques of Byzantine and Late Roman ceramics were nearly similar.

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使用 XRD、WD-XRF 和 SEM/EDX 分析研究中世纪考古陶瓷

使用考古测量技术检查了从 Zeytinli 岛（土耳其埃尔德克）发掘中获得的一些中世纪陶瓷发现。首先，使用Munsell颜色系统确定编码和拍照的陶瓷样品的颜色值。通过扫描电子显微镜/能量色散 X 射线 (SEM/EDX)、波长色散 X 射线荧光 (WD-XRF) 和 X 射线衍射法 (XRD) 分析确定样品的形态结构、化学和矿物学含量。通过观察 SEM、XRD 和 XRF 测量的元素和颜色分析，获得有关陶瓷的基质、矿物相、粒度、聚集体含量和孔隙率的信息。在公元 6 世纪和 7 世纪的陶瓷样品中发现了石英、蛭石、海泡石、伊利石、方解石、赤铁矿矿物相（S1、S2、S3) 通过评估获得的 XRD 测量结果。除了其他相之外，在公元 13 世纪的陶瓷中还观察到了柏林石、卡拉科莱特和顽火石相。在陶瓷样品中，发现了大量的 O、Mg、Al、Si 和 Ca 元素。二氧化硅_{发现 2}和 Al ₂ O ₃化合物的浓度分别为 67.37-52.95% 和 34.39-15.65%。观察到痕量的Cu、Sr、Rb、Ni和Mn等元素。在东方教堂出土的所研究陶瓷的釉料中发现了铅元素。SEM-EDX 分析表明，烧制良好的陶瓷样品的表面具有均匀的结构。根据WD-XRF分析结果可以看出，拜占庭陶瓷和晚期罗马陶瓷的化学成分和生产工艺几乎相似。