Performance and future directions of transition metal sulfide-based electrode materials towards supercapacitor/supercapattery,Wiley Interdisciplinary Reviews: Energy and Environment

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Performance and future directions of transition metal sulfide-based electrode materials towards supercapacitor/supercapattery
Wiley Interdisciplinary Reviews: Energy and Environment ( IF 5.4 ) Pub Date : 2021-07-01 , DOI: 10.1002/wene.414
Arya Das _{1,

2} , Benjamin Raj ₁ , Mamata Mohapatra _{1,

2} , Shuang Ma Andersen ₃ , Suddhasatwa Basu ₁

Affiliation

Advanced and sustainable energy storage technologies with tailorable electrochemically active materials platform are the present research dominancy toward an urgent global need for electrical vehicles and portable electronics. Moreover, intensive efforts are given to screen the widely available low-cost materials with a focus to achieve superior electrochemical performance for the fabrication of energy storage devices. Transition metal-based sulfides have prodigious technological credibility due to their compositional- and morphological-based tunable electrochemical properties. Here the significant advances and present state-of-the-art of such assured materials in different energy storage devices are discussed. Assessment of the intensive work invested in the progress of transition metals such as V, Mn, Fe, Co, Ni, Cu, Zn Mo, and W based sulfides along with their structural/compositional engineering and addressable aspects for electrochemical performance enhancement are highlighted. Additionally, discussions on critical strategies for decisive mechanistic and kinetic views for charge storage phenomena with key challenges, such as volume expansions, low stability, and sluggish kinetics, are discussed. Finally, the challenges and future prospects demands for strategic approaches of such materials with prominence in futuristic directions are concluded.

中文翻译：

过渡金属硫化物基电极材料在超级电容器/超级电容器方面的性能和未来方向

具有可定制电化学活性材料平台的先进和可持续的储能技术是目前全球对电动汽车和便携式电子产品的迫切需求的研究主导。此外，人们努力筛选广泛可用的低成本材料，重点是实现卓越的电化学性能，用于制造储能装置。过渡金属基硫化物由于其基于成分和形态的可调电化学特性而具有惊人的技术可信度。这里讨论了在不同储能设备中这种有保证的材料的重大进展和目前的最新技术。评估在 V、Mn、Fe、Co、Ni、Cu、Zn Mo 等过渡金属的进展中投入的大量工作，重点介绍了基于 W 和 W 的硫化物以及它们的结构/组成工程和电化学性能增强的可寻址方面。此外，还讨论了具有关键挑战的电荷存储现象的决定性机械和动力学观点的关键策略，例如体积膨胀、低稳定性和缓慢的动力学。最后，总结了未来方向突出的此类材料的战略方法所面临的挑战和未来前景需求。和缓慢的动力学，进行了讨论。最后，总结了未来方向突出的此类材料的战略方法所面临的挑战和未来前景需求。和缓慢的动力学，进行了讨论。最后，总结了未来方向突出的此类材料的战略方法所面临的挑战和未来前景需求。

更新日期：2021-07-01

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