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Synthesis of 1,2-diketones by mercury-catalyzed alkyne oxidation
Synthetic Communications ( IF 1.8 ) Pub Date : 2021-06-30 , DOI: 10.1080/00397911.2021.1946082 Xiaochuan Mei 1 , Weican Hu 1 , Kexin Gao 1 , Haotian Gao 1 , Chaoyang Wang 1 , Guoying Qian 1 , Zhouting Rong 1
中文翻译:
汞催化炔氧化合成 1,2-二酮
更新日期:2021-08-23
Synthetic Communications ( IF 1.8 ) Pub Date : 2021-06-30 , DOI: 10.1080/00397911.2021.1946082 Xiaochuan Mei 1 , Weican Hu 1 , Kexin Gao 1 , Haotian Gao 1 , Chaoyang Wang 1 , Guoying Qian 1 , Zhouting Rong 1
Affiliation
Abstract
The first mercury-catalyzed synthesis of 1,2-diketones by alkyne oxidation has been developed. This inexpensive method extends the potential of mercury catalysis and allows the rapid construction of various 1,2-diketones and α-carbonyl amides in good yields with high functional group tolerance.
中文翻译:
汞催化炔氧化合成 1,2-二酮
摘要
已经开发出第一个通过炔烃氧化在汞催化下合成 1,2-二酮。这种廉价的方法扩展了汞催化的潜力,并允许以高收率和高官能团耐受性快速构建各种 1,2-二酮和 α-羰基酰胺。