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Synthesis of indoles, indolines, and carbazoles via palladiumcatalyzed C ¨C H activation
Green Synthesis and Catalysis ( IF 8.2 ) Pub Date : 2021-6-20 , DOI: 10.1016/j.gresc.2021.02.001 Alexander J Rago 1 , Guangbin Dong 1
Green Synthesis and Catalysis ( IF 8.2 ) Pub Date : 2021-6-20 , DOI: 10.1016/j.gresc.2021.02.001 Alexander J Rago 1 , Guangbin Dong 1
Affiliation
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Indoles and their close derivatives, indolines and carbazoles, have been of
interest to synthetic chemists due to their prevalence in natural products
and biologically active molecules. In particular, the activation of inert C ¨C H
bonds presents an elegant means to prepare these heterocycles from simple
precursors. This review will highlight the versatility of palladium-catalyzed C ¨C H
activation for the preparation of indoles, indolines, and carbazoles, discussing
intramolecular cyclization and multi-component ring construction strategies.
中文翻译：
钯催化C-CH活化合成吲哚、二氢吲哚和咔唑
吲哚及其紧密衍生物二氢吲哚和咔唑因其在天然产物和生物活性分子中的普遍存在而引起合成化学家的兴趣。特别是，惰性 C-CH 键的活化为从简单的前体制备这些杂环提供了一种优雅的方法。本综述将重点介绍钯催化的 C-CH 活化制备吲哚、二氢吲哚和咔唑的多功能性，讨论分子内环化和多组分环构建策略。
更新日期：2021-06-30
中文翻译：
钯催化C-CH活化合成吲哚、二氢吲哚和咔唑
吲哚及其紧密衍生物二氢吲哚和咔唑因其在天然产物和生物活性分子中的普遍存在而引起合成化学家的兴趣。特别是，惰性 C-CH 键的活化为从简单的前体制备这些杂环提供了一种优雅的方法。本综述将重点介绍钯催化的 C-CH 活化制备吲哚、二氢吲哚和咔唑的多功能性，讨论分子内环化和多组分环构建策略。
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