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Experimental Investigation of Phase Equilibria in the Cu–Cr–Ti System
Journal of Phase Equilibria and Diffusion ( IF 1.5 ) Pub Date : 2021-06-29 , DOI: 10.1007/s11669-021-00892-y
J. H. Li , X. M. Huang , L. L. Zhu , G. M. Cai

To provide a basic guide for the design of Cu–Cr-based alloys, phase equilibrium relations in the Cu–Cr–Ti system have been studied using diffusion triples and typical equilibrated alloys. Based on the results from electron-probe microscopy analysis and x-ray diffraction, isothermal sections of the Cu–Cr–Ti ternary system at 1073 and 973 K were constructed, wherein 9 and 11 three-phase equilibria were determined, respectively. A ternary phase with an approximate composition of (Cu, Cr)4Ti3 was detected and named as τ1. The binary Cu4Ti3 phase does not connect with τ1 in the ternary region. Solid solution phases (Cu, Cr)3Ti2 and τ1 were identified and confirmed in both diffusion triple and alloy samples. The solubility of Cr in Cu3Ti2 extends to 12 at.% at both 1073 and 973 K. (Cu, Cr)3Ti2 and Cu3Ti2 form a continuous solid solution at 1073 K while do not exist as one stable phase at 973 K. In addition, two two-phase regions of Cu4Ti + (Cu, Cr)3Ti2 and Cu4Ti3 + (Cu, Cr)3Ti2 transform to the three-phase regions of Cu4Ti + Cu4Ti3 + (Cu, Cr)3Ti2 as the temperature decreases from 1073 to 973 K.



中文翻译:

Cu-Cr-Ti体系相平衡的实验研究

为了为 Cu-Cr 基合金的设计提供基本指导,使用扩散三元组和典型的平衡合金研究了 Cu-Cr-Ti 系统中的相平衡关系。基于电子探针显微镜分析和 X 射线衍射的结果,构建了 Cu-Cr-Ti 三元体系在 1073 和 973 K 的等温截面,其中分别确定了 9 个和 11 个三相平衡。检测到组成近似为 (Cu, Cr) 4 Ti 3的三元相并将其命名为 τ 1。二元Cu 4 Ti 3相在三元区不与τ 1连接。固溶相 (Cu, Cr) 3 Ti 2和 τ1在扩散三元组和合金样品中均得到鉴定和确认。Cr 在 Cu 3 Ti 2 中的溶解度在 1073 K 和 973 K 时均扩展到 12 at.%。 (Cu, Cr) 3 Ti 2和 Cu 3 Ti 2在 1073 K 形成连续固溶体,但不以稳定形式存在相在 973 K。此外,Cu 4 Ti + (Cu, Cr) 3 Ti 2和 Cu 4 Ti 3  + (Cu, Cr) 3 Ti 2的两个两相区域转变为 Cu 4的三相区域Ti + Cu 4 Ti 3  + (Cu, Cr)3 Ti 2随着温度从 1073 K 降低到 973 K。

更新日期:2021-06-29
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