Abstract

A series of 9-position substituted triptycene derivatives were synthesized from 9-substituted anthracenes. Diels–Alder reaction was the key reaction to form the scaffold; both benzoquinon and aryne were studied as dienophile. The diastereomers of triptycene 10a were separated by chiral high-performance liquid chromatography (HPLC) column.

中文翻译：

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9-取代三萜衍生物的实用合成

摘要

由 9-位取代的蒽合成了一系列 9-位取代的三苯乙烯衍生物。Diels-Alder 反应是形成支架的关键反应；苯醌和亚芳基均作为亲二烯体进行研究。通过手性高效液相色谱 (HPLC) 柱分离三苯乙烯 10a 的非对映异构体。