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1D Zn2GeO4 rods supported on Ni foam for high performance non-enzymatic hydrogen peroxide sensor
Surfaces and Interfaces ( IF 5.7 ) Pub Date : 2021-06-24 , DOI: 10.1016/j.surfin.2021.101295
Nanyu Fan , Quan Kong , Ruifeng Lang , Hongtao Guan , Gang Chen , Chengjun Dong

One-dimensional (1D) Zn2GeO4 rods were in-situ grown on Ni foam (NF) using a ethylenediamine (En)/water mixed solvent by a hydrothermal route in one single step. Such rhombohedral phase Zn2GeO4 rods are 1-2 μm in diameter and a few micrometers in length. Ethylenediamine is found to play a critical role in coordinating with starting zinc and germanium ions and acting as template. The Zn2GeO4/NF was developed as a new none-enzymatic hydrogen peroxide (H2O2) sensor. In electrochemical studies, the Zn2GeO4/NF electrode exhibits high sensitivity (3974 μM M m−1 cm−2), wide linear detection range (1-4000μM), fast response (< 9 s), low detection limit (1 μM), excellent selectivity and stability towards H2O2. Several factors such as intrinsic nature of Zn2GeO4, the unique microstructure and the seamless contact with NF are believed to attributed to the excellent electrochemical sensing performances.



中文翻译:

1D Zn 2 GeO 4棒支撑在泡沫镍上,用于高性能非酶促过氧化氢传感器

一维 (1D) Zn 2 GeO 4棒使用乙二胺 (En)/水混合溶剂通过水热途径一步在镍泡沫 (NF) 上原位生长。这种菱形相Zn 2 GeO 4棒的直径为1-2μm,长度为几微米。发现乙二胺在与起始锌和锗离子配位和充当模板方面起着关键作用。Zn 2 GeO 4 /NF 被开发为一种新的非酶促过氧化氢 (H 2 O 2 ) 传感器。在电化学研究中,Zn 2 GeO 4 /NF 电极表现出高灵敏度 (3974 μM M m -1cm -2 )、宽线性检测范围 (1-4000μM)、快速响应 (< 9 s)、低检测限 (1 μM)、出色的选择性和对 H 2 O 2 的稳定性。Zn 2 GeO 4 的固有性质、独特的微观结构和与NF的无缝接触等几个因素被认为归因于优异的电化学传感性能。

更新日期:2021-06-24
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