Two new 3-dimensional (3D) 3d-4f bimetal organic frameworks (ZnCe-MOF and CuCe-MOF) were created through hydrothermal method. These MOFs have the similar formula (M₂(imidazole)₂Ce(H₂O)(C₂O₄)_1/2(4,5-ida)₂·2(H₂O), M = Zn, Cu; 4,5-ida: 4,5-imidazole dicarboxylate) and possesses monoclinic symmetry in the P2₁/n space group. The electrodeposition method was used to in-situ coat polyaniline (PANI) to improve the electrical conductivity. As the electrode materials for supercapacitors in three-electrode system, the specific capacitance of CuCe-MOF@PANI-1 and ZnCe-MOF@PANI-1 electrodes can reach 724.4F g⁻¹ and 713.2F g⁻¹ at 1 A g⁻¹. Using the as-synthesized CuCe-MOF@PANI-1 heteorostructure as positive material, the assembled hybrid capacitor delivers an energy density of 87.45 Wh kg⁻¹ and 58.05 Wh kg⁻¹ at power density of 850 W kg⁻¹, demonstrating that the heteorostructure of MOF coated with PANI has promising applications in portable energy storage devices.

通过水热法创建了两种新的 3 维（3D）3d-4f 双金属有机骨架（ZnCe-MOF 和 CuCe-MOF）。这些MOFs具有相似的分子式(M ₂ (imidazole) ₂ Ce(H ₂ O)(C ₂ O ₄ ) _1/2 (4,5-ida) ₂ ·2(H ₂ O)，M = Zn，Cu； 4,5-ida：4,5-咪唑二羧酸酯）并且在P2 ₁ /n 中具有单斜对称性空间群。电沉积方法用于原位涂覆聚苯胺（PANI）以提高电导率。作为三电极体系中超级电容器的电极材料，CuCe-MOF@PANI-1和ZnCe-MOF@PANI-1电极的比电容在1 A g ^{- 下}可达到724.4F g ^-1和713.2F g ^{-1 1} . 使用合成的 CuCe-MOF@PANI-1 异质结构作为正极材料，组装的混合电容器在 850 W kg ^{-1 的}功率密度下提供 87.45 Wh kg ^-1和 58.05 Wh kg ^-1的能量密度，证明了涂有 PANI 的 MOF 异质结构在便携式储能设备中具有广阔的应用前景。