当前位置: X-MOL 学术Int. J. Thermophys. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Density Measurements of an Air-Like Binary Mixture over the Temperature Range from 100 K to 298.15 K at Pressures up to 8.0 MPa
International Journal of Thermophysics ( IF 2.5 ) Pub Date : 2021-06-24 , DOI: 10.1007/s10765-021-02871-4
Nils von Preetzmann , Reiner Kleinrahm , Philipp Eckmann , Giuseppe Cavuoto , Markus Richter

Densities of an air-like binary mixture (0.2094 oxygen + 0.7906 nitrogen, mole fractions) were measured along six isotherms over the temperature range from 100 K to 298.15 K at pressures up to 8.0 MPa, using a low-temperature single-sinker magnetic suspension densimeter. The measurements were carried out at T = (100, 115, and 130) K in the homogeneous gas and liquid region, and at T = (145, 220, and 298.15) K in the supercritical region (critical temperature TC = 132.35 K); in total, we present results for 52 (T, p) state points. The relative expanded combined uncertainty (k = 2) of the experimental densities was estimated to be between 0.03 % and 0.13 %, except for four values near the critical point. The largest error is caused by the magnetic suspension coupling in combination with the mixture component oxygen, which is strongly paramagnetic; the resulting force transmission error is up to 1.1 %. However, this error can be corrected with a proven correction model to an uncertainty contribution in density of less than 0.044 %. Due to a supercritical liquefaction procedure and the integration of a special VLE-cell, it was possible to measure densities in the homogeneous liquid phase without changing the composition of the liquefied mixture. Moreover, saturated liquid and saturated vapor densities were determined at T = (100, 115, and 130) K by extrapolation of the experimental single-phase densities to the saturation pressure. The new experimental results were compared with the mixture model of Lemmon et al. for the system (nitrogen + argon + oxygen) and the GERG-2008 equation of state.



中文翻译:

在 100 K 至 298.15 K 的温度范围内,在高达 8.0 MPa 的压力下测量类空气二元混合物的密度

使用低温单沉降器磁悬浮,在 100 K 至 298.15 K 的温度范围内,在 100 K 至 298.15 K 的温度范围内,测量了类空气二元混合物(0.2094 氧 + 0.7906 氮,摩尔分数)的密度密度计。测量是在执行Ť  =(100,115和130)K均相气体和液体区域中,并且在Ť  =(145,220和298.15)K在该超临界区域(临界温度Ť Ç  = 132.35ķ ); 总的来说,我们展示了 52 个(Tp)状态点的结果。相对扩展组合不确定度 ( k = 2) 的实验密度估计在 0.03 % 和 0.13 % 之间,除了临界点附近的四个值。最大的误差是由磁悬浮耦合与混合成分氧结合引起的,它是强顺磁性的;由此产生的力传递误差高达 1.1%。但是,可以使用经过验证的校正模型来校正此误差,使密度的不确定性贡献小于 0.044 %。由于超临界液化程序和特殊 VLE 单元的集成,可以在不改变液化混合物的组成的情况下测量均相液相中的密度。此外,饱和液体和饱和蒸气密度在T = (100, 115, 和 130) K 通过将实验单相密度外推到饱和压力。新的实验结果与 Lemmon等人的混合模型进行了比较。对于系统(氮 + 氩 + 氧)和 GERG-2008 状态方程。

更新日期:2021-06-24
down
wechat
bug