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Boosting the selectivity of aromatic hydrocarbons via ex-situ catalytic fast pyrolysis of cellulose over Pt–Sn–Ce/γ-Al2O3 catalyst
Journal of the Energy Institute ( IF 5.6 ) Pub Date : 2021-06-24 , DOI: 10.1016/j.joei.2021.06.014
Wenbin Li , Jida Wang , Zhen Wang , Jie Chen , Xiaoan Nie , Zhangshuai Ding , Dechao Wang , Zhifeng Zheng , Yunwu Zheng , Jianchun Jiang

Pt–Sn–Ce/γ-Al2O3 catalysts were synthesized by the impregnation method and used to produce aromatic hydrocarbons (AHs)-rich bio-oil via catalytic fast pyrolysis of cellulose. The upgraded products were on-line analyzed by pyrolysis-comprehensive two-dimensional gas chromatography/mass spectrometry (Py-GC × GC/MS). It was found that Pt–Sn–Ce/γ-Al2O3 catalysts were effective for improving the relative content of AHs in bio-oil. Especially, Pt–Sn–Ce/γ-Al2O3 contributed the highest AHs content (85.82%), which was 3 times than that of γ-Al2O3, and increased 85.44% compared with non-catalytic. In addition, Pt–Sn–Ce/γ-Al2O3 and Pt–Sn/γ-Al2O3 can generate the highest monocyclic aromatic hydrocarbons (MAHs) with the relative content of 60.24% and 51.92%, respectively. Pt–Sn–Ce/γ-Al2O3 catalyst can be reused five times with stable catalytic activity to produce AHs-rich bio-oil.



中文翻译:

Pt-Sn-Ce/γ-Al 2 O 3催化剂上纤维素的异位催化快速热解提高芳烃的选择性

Pt-Sn-Ce/γ-Al 2 O 3催化剂通过浸渍法合成,并用于通过纤维素的催化快速热解生产富含芳烃(AHs)的生物油。升级后的产品通过热解综合二维气相色谱/质谱(Py-GC × GC/MS)进行在线分析。结果表明,Pt-Sn-Ce/γ-Al 2 O 3催化剂可有效提高生物油中AHs的相对含量。其中,Pt-Sn-Ce/γ-Al 2 O 3的AHs含量最高(85.82%),是γ-Al 2 O 3 的3倍,比非催化增加了85.44%。此外,Pt-Sn-Ce/γ-Al 2O 3和Pt-Sn/γ-Al 2 O 3可以生成最高的单环芳烃(MAHs),相对含量分别为60.24%和51.92%。Pt-Sn-Ce/γ-Al 2 O 3催化剂可以重复使用5次,具有稳定的催化活性,可以生产富含AHs的生物油。

更新日期:2021-06-28
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