Among the different types of specialty polymers, polysiloxane finds its position in the pyramid's apex in terms of its performance attributes. Its unique structural features result in it having superior performance benefits over wide operational conditions. Hence, polysiloxanes are used in various industries. Like other polymers, to effectively use polysiloxanes, curing is a non-negotiable fact. Therefore, polysiloxanes are cured using different chemistries such as addition, condensation, and peroxy-mediated methods, etc. However, recently, it has been noted that there is a strong impetus towards developing radiation-curable polysiloxanes. A faster turnover time, higher yield, and marginal involvement in the release of any toxic by-products has resulted in the widespread acceptance of radiation curing techniques. This review article provides insight into the various facets of polysiloxane chemistry, the synthesis of radiation curable polysiloxane, and the curing methodology of polysiloxane using radiation sources such as ultraviolet, electron beam, and gamma radiation. We further provide an account of the various applications of such radiation-curable polysiloxanes.

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辐射固化聚硅氧烷：合成到应用

在不同类型的特种聚合物中，聚硅氧烷在其性能属性方面处于金字塔的顶端。其独特的结构特点使其在广泛的操作条件下具有卓越的性能优势。因此，聚硅氧烷用于各种行业。与其他聚合物一样，要有效地使用聚硅氧烷，固化是一个不容商量的事实。因此，聚硅氧烷使用不同的化学物质进行固化，例如加成、缩合和过氧介导的方法等。然而，最近，人们注意到开发可辐射固化的聚硅氧烷有强大的推动力。更快的周转时间、更高的产量以及对任何有毒副产品释放的微不足道的参与已经导致辐射固化技术被广泛接受。这篇评论文章深入探讨了聚硅氧烷化学的各个方面、可辐射固化聚硅氧烷的合成以及使用紫外线、电子束和伽马辐射等辐射源的聚硅氧烷固化方法。我们进一步提供了此类可辐射固化聚硅氧烷的各种应用的说明。