Micro and Nanostructures ( IF 2.7 ) Pub Date : 2021-06-22 , DOI: 10.1016/j.spmi.2021.106974 Hai Ma , Xiaodan Wang , Jiafan Chen , Xiaodong Gao , Shunan Zheng , Hongmin Mao , Dan Wang , Xionghui Zeng , Ke Xu
X-Ray diffraction (XRD), Raman scattering, Cathodoluminescence measurements (CL) and Photoluminescence (PL) were employed to characterize the structure and optical properties of Dysprosium (Dy) and Europium (Eu) implanted GaN films grown by MOCVD. For GaN: Dy3+ samples, Dy3+ implantation leads to strain and radiation damage increasing with Dy3+ implanted fluence. From the CL spectra, the characteristic transitions from the excited 4F9/2 level of Dy3+ to 6H15/2 (485 nm), 6H13/2 (583 nm) and 6H11/2 (671 nm) were observed. For Dy3+ and Eu3+ co-doped GaN, considering the doping effects of Dy3+, we proposed that there might exist a resonance energy transfer process from Eu3+ ions 7F0→5D2 to Dy3+ ions 4F9/2 → 6H15/2, which is dominated by the electric dipole-dipole interaction.
中文翻译:
Eu 3+和Dy 3+注入GaN薄膜的结构和发光特性
X 射线衍射 (XRD)、拉曼散射、阴极发光测量 (CL) 和光致发光 (PL) 被用来表征通过 MOCVD 生长的镝 (Dy) 和铕 (Eu) 注入 GaN 薄膜的结构和光学特性。对于GaN:Dy 3+样品,Dy 3+注入导致应变和辐射损伤随着Dy 3+注入注量的增加而增加。从 CL 光谱,特征跃迁从Dy 3+的激发4 F 9/2能级到6 H 15/2 (485 nm)、6 H 13/2 (583 nm) 和6 H 11/2 (671 nm) ) 被观察到。对于 Dy3+和 Eu 3+共掺杂的 GaN,考虑到 Dy 3+的掺杂效应,我们提出可能存在 Eu 3+离子7 F 0 → 5 D 2到 Dy 3+离子4 F的共振能量转移过程9/2 → 6 H 15/2,主要是电偶极-偶极相互作用。